苄基铯 | 19104-13-3

• 中文名称: 苄基铯
• 英文名称: benzyl cesium
• 英文别名: benzyl caesium；benzylcesium；Benzylcaesium
• CAS: 19104-13-3
• 化学式: C₇H₇Cs
• 分子量: 224.038
• InChiKey: HLZIGZQAUDKTBR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.36
• 重原子数：
  8.0
• 可旋转键数：
  1.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  苄基铯 、 三乙基氢化锗 生成 甲苯
  参考文献：
  名称：

  BRAVO-ZHIVOTOVSKIJ, D. A.;PIGAREV, S. D.;VYAZANKINA, O. A.;VYAZANKIN, N. +, ZH. OBSHCH. XIMII, 57,(1987) N 12, 2735-2738

  摘要：

  DOI：
• 作为产物：
  描述：

  1,2-二苯乙烷 以93%的产率得到
  参考文献：
  名称：

  GROVENSTEIN, ERLING, JR.;QUEST, DEAN E.;SENGUPTA, DIBYENDU, ORGANOMET. SYNTH. VOL. 3, AMSTERDAM E. A.,(1986) 387-388

  摘要：

  DOI：
• 作为试剂：
  描述：

  叠氮金刚烷 在 苄基铯 作用下， 以 四氢呋喃 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Group 1 Bis(iminophosphorano)methanides, Part 1: N-Alkyl and Silyl Derivatives of the Sterically Demanding Methanes H₂C(PPh₂NR)₂ (R = Adamantyl and Trimethylsilyl)

  摘要：

  Treatment of [Li{HC(PPh2NSiMe3)(2)}](2) with 2 equiv of [MOR] (M = Rb, Cs; OR = 2-ethylhexoxide) afforded the heavy group 1 methanides [Rb{HC(PPh2NSiMe3)(2)} (THF)(2)] (1) and [Cs{HC(PPh2NSiMe3)(2)}(DME)(2)] (2), which do not exhibit methanide C center dot center dot center dot M contacts in the solid state. Following a literature procedure, H2C(PPh2)(2) was reacted with 2 equiv of AdN(3) (Ad = adamantyl) to give H2C(PPh(2)NAd)(2) (3). Reaction of 3 with 1 equiv of (BuLi)-Li-t in toluene afforded dimeric [Li{HC(PPh(2)NAd)(2)}](2) (4). Treatment of 3 with 1 equiv of [M(Bn)] (M = Na, K; Bn = CH2C6H5) in THF gave the Lewis base adducts [M{HC(PPh(2)NAd)(2)}(THF)(2)] [M = Na (5), K (6)]. The heavy group 1 methanides [Rb{HC(PPh(2)NAd)(2)}(THF)(2)] (7) and [Cs{HC(PPh(2)NAd)(2)}(DME)(2)] (8) were prepared by the reaction of [MOR] (M = Rb, Cs; OR = 2-ethylhexoxide) with 4 or reaction of [Cs(Bn)] with 3. The synthetic utility of these group 1 transfer agents has been demonstrated by the preparation of [La{HC(PPh2NR)(2)}(I)(2)(THF)] [R = SiMe3 (9), Ad (10)] from [La(I)(3)(THF)(4)], employing a salt metathesis methodology. Complexes 1-10 have been characterized by X-ray crystallography, multielement NMR spectroscopy, FTIR spectroscopy, and CHN microanalyses.

  DOI：

  10.1021/om200553s

文献信息

• The preparation of pure allyl- and benzyl-type organoalkali intermediates via organotin compounds
  作者：Olivier Desponds、Manfred Schlosser

  DOI：10.1016/0022-328x(91)86134-c

  日期：1991.5

  alkylbenzenes and subsequent condensation with trialkylstannyl chloride affords allyl- or benzyl-type organotin compounds that can be isolated in pure form. Treatment with soluble reagents such as methyllithium, trimethylsilylmethylpotassium and trimethylsilylmethylcaesium generates the corresponding organoalkali derivatives almost quantitatively and in high purity, suitable for kinetic or spectroscopic studies

  烯烃或烷基苯的超碱金属化，然后与三烷基锡烷基氯缩合，可得到可以纯净形式分离的烯丙基或苄基型有机锡化合物。用诸如甲基锂，三甲基甲硅烷基甲基钾和三甲基甲硅烷基甲基铯的可溶性试剂处理几乎可以定量且高纯度地产生相应的有机碱衍生物，适用于动力学或光谱研究。
• β-Diketiminate Derivatives of Alkali Metals and Uranium
  作者：Ashley J. Wooles、William Lewis、Alexander J. Blake、Stephen T. Liddle

  DOI：10.1021/om400435b

  日期：2013.9.23

  Treatment of [M(Bn)] (M = K, Cs) with [HCC(Bu-t)NDipp}C(Bu-t)-NHDipp}] ((LH)-H-But; Dipp = 2,6-diisopropylphenyl) afforded [K(L-But)(THF)(n)], 1, and [Cs(L-But)], 2, which were crystallized from hexane or benzene to afford [K(L-But)-(THF)(3)], 1a, and [Cs(L-But)}Cs(L-But)(eta(3)-C6D6))-C6D8](infinity), 2a, respectively. Complexes 1 and 2 were utilized in the preparation of the previously reported [U(L-But)Cl-3], which was cleanly converted to [U(L-But)I-3], 3, via reaction with an excess of Me3SiI. Attempts to prepare U(III) complexes incorporating the L-But ligand proved unsuccessful, but utilizing [HCC(Me)NDipp}(C(Me)NHDippl] ((LH)-H-Me) led to the isolation of [U(L-Me)(2)(THF)(2)], 4, via the reaction of [K(L-Me)] with [U(I)(3)(THF)(4)]. Complex 4 can be derivatized via reaction with [K(Cp*)] (Cp* = eta(5)-C5Me5) or [KN(SiMe3)(2)}] to afford [U(L-Me)(Cp*)I], 5, and [U(L-Me)N(SiMe3)(2)}I], 6, respectively. The reaction of 4 with two equivalents of [KN(SiMe3)(2)}] did not afford [U(L-Me)N(SiMe3)(2)}(2)] as expected, but instead led to the isolation of the U(IV) species [UHC[C(Me)NDipp]-[C(CH2)NDipp]}N(SiMe3)(2)}(2)], 7, via deprotonation of the L-Me ligand. The reduction of 4 with KC8 in benzene afforded the diuranium inverse sandwich complex [U(L-Me)I}(2)(mu-eta(6):eta(6)-C6H6)], 8, albeit in low yield. Complexes 1-8 have been characterized by single-crystal X-ray diffraction studies, by multielement NMR spectroscopy, and variously by FTIR spectroscopy, elemental analysis, UV/vis/NIR spectroscopy, and solution-state magnetic studies.
• Orzechowski, Lars; Jansen, Georg; Harder, Sjoerd, Angewandte Chemie - International Edition, 2009, vol. 48, p. 3825 - 3829
  作者：Orzechowski, Lars、Jansen, Georg、Harder, Sjoerd

  DOI：——

  日期：——
• Vanermen, Guido; Toppet, Suzanne; Van Beylen, Marcel, Journal of the Chemical Society. Perkin transactions II, 1986, p. 707 - 714
  作者：Vanermen, Guido、Toppet, Suzanne、Van Beylen, Marcel、Geerlings, Paul

  DOI：——

  日期：——
• Dissociation behavior of benzylalkali compounds in tetrahydrofuran: effect of countercation, aromatic methoxy substitution, and .alpha.-alkyl substitution
  作者：G. Vanermen、M. Van Beylen、P. Geerlings

  DOI：10.1021/j100276a024

  日期：1986.2