[Ru(tpy)(N,N'-HOtpy)Cl](PF6) | 878047-57-5

• 英文名称: [Ru(tpy)(N,N'-HOtpy)Cl](PF6)
• 英文别名: [Ru(2,2':6',2''-terpyridine)(N,N'-4'-hydroxy-2,2':6',2''-terpyridine)Cl](PF6)
• CAS: 878047-57-5
• 化学式: C₃₀H₂₂ClN₆ORu*F₆P
• 分子量: 764.031
• InChiKey: DZLPHMXHMJYMFX-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 Ru(tpy)(Cl)₃ 、 2,6-双(2-吡啶基)-4(1H)-吡啶酮 在 N-乙基吗啉 作用下， 以 甲醇 、 水 、 乙腈 为溶剂， 以21%的产率得到[Ru(tpy)(N,N'-HOtpy)Cl](PF6)
  参考文献：
  名称：

  Conventional and metal-directed synthesis of homodinuclear and heterotrinuclear complexes of homoditopic and heteroditopic ligands incorporating bpy and tpy metal-binding domains

  摘要：

  Strategies for the preparation of multinuclear complexes containing homoditopic and heteroditopic ligands based upon 2,2$-bipyridine (bpy) and 2,2:6$,2$$-terpyridine metal binding domains are presented. Both conventional approaches based upon preparation of a free ligand and subsequent coordination and metal-directed reactions of coordinated ligands are utilized in the various strategies. A representative series of complexes of these ligands has been prepared. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2005.07.007