Phosphorane Iminato Complexes of Manganese and Cobalt with Heterocubane Structure
摘要:
Mn4N4 and Co4N4 cubes with almost square faces are found in the title compounds 1 and 2. They were obtained by the melt reaction of the anhydrous dihalides MnI2 and CoCl2, and Me3SiNPEt3. Complexes 1 and 2 are the first phosphorane iminato complexes of manganese(II) and cobalt(II) with heterocubane structure. equation image