trans-tetrabromobis(3,5-dimethylpyridine)germanium(IV) | 253444-13-2

• 英文名称: trans-tetrabromobis(3,5-dimethylpyridine)germanium(IV)
• CAS: 253444-13-2
• 化学式: C₁₄H₁₈Br₄GeN₂
• 分子量: 606.516
• InChiKey: RKVCXSJQWJWWMJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3,5-二甲基吡啶 、 溴化锗 以 正戊烷 为溶剂， 生成 trans-tetrabromobis(3,5-dimethylpyridine)germanium(IV)
  参考文献：
  名称：

  trans-Tetrabromobis(3,5-dimethylpyridine)germanium(IV), a non-merohedral twin

  摘要：

  The structure of the title compound, [GeBr4(C7H9N)(2)], is the first example of an addition compound of GeBr4 with two aromatic nitrogen bases. The molecule, with D-2h symmetry, has crystallographic C-2h Site symmetry. The environment around the Ge atom can be described as a slightly distorted octahedron with the dimethyl-pyridine ligands occupying axial positions and the four bromo ligands in the equatorial plane. The crystal structure is a non-merohedral twin composed of two overlapping monoclinic domains, simulating an orthorhombic symmetry.

  DOI：

  10.1107/s0108270199010409