trans-dibromobis(N,N,N',N'-tetramethylethane-1,2-diamine)nickel(II) | 344792-49-0

• 英文名称: trans-dibromobis(N,N,N',N'-tetramethylethane-1,2-diamine)nickel(II)
• CAS: 344792-49-0
• 化学式: C₁₂H₃₂Br₂N₄Ni
• 分子量: 450.911
• InChiKey: VJZRLJDHPDHMKJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  trans-dibromobis(N,N,N',N'-tetramethylethane-1,2-diamine)nickel(II) 以 neat (no solvent) 为溶剂， 以61%的产率得到nickel(II) bromide ethylene glycol dimethyl ether
  参考文献：
  名称：

  Triangulo-pentahalotrimetal complexes of nickel(II) and cobalt(II) with N,N,N′,N′,N-tetramethylethane-1,2-diamine and related compounds

  摘要：

  Nickel(ll) and cobalt(II) form complexes [M3Cl5(neutral didentate ligand)(3)](+) containing the triangulo-trihalotrimetal moieties with considerable case, and they are very similar in structure to the known titanium, vanadium, and iron homologues. However, chromium and copper are not. The supporting neutral ligand is almost invariably N,N,N',N'-tetramethylethane-1,2-diamine. These compounds show a great affinity fur water and react to lose one apical chloride to be replaced by hydroxide. The analogous bromide derivatives have also been prepared and characterised. For the first time, a triangulo-trihalotrimetal compound containing fluoride has also been prepared. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00383-2
• 作为产物：
  描述：

  四氢呋喃 、 四甲基乙二胺 、 nickel dibromide 以 四氢呋喃 为溶剂， 以29%的产率得到[Ni3Br5(N,N,N',N'-tetramethylethane-1,2-diamine)3]Br*tetrahydrofuran
  参考文献：
  名称：

  Triangulo-pentahalotrimetal complexes of nickel(II) and cobalt(II) with N,N,N′,N′,N-tetramethylethane-1,2-diamine and related compounds

  摘要：

  Nickel(ll) and cobalt(II) form complexes [M3Cl5(neutral didentate ligand)(3)](+) containing the triangulo-trihalotrimetal moieties with considerable case, and they are very similar in structure to the known titanium, vanadium, and iron homologues. However, chromium and copper are not. The supporting neutral ligand is almost invariably N,N,N',N'-tetramethylethane-1,2-diamine. These compounds show a great affinity fur water and react to lose one apical chloride to be replaced by hydroxide. The analogous bromide derivatives have also been prepared and characterised. For the first time, a triangulo-trihalotrimetal compound containing fluoride has also been prepared. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(00)00383-2