| 102286-21-5

• CAS: 102286-21-5
• 化学式: C₁₉H₁₅ClMoN₂O₂
• 分子量: 434.733
• InChiKey: QNSQCBHGEJCRPN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三甲氧基磷 以 二氯甲烷 为溶剂， 以66%的产率得到benzylidyne(chloro)molybdenum;carbon monoxide;trimethyl phosphite
  参考文献：
  名称：

  三和四（亚磷酸三甲酯）取代的铬，钼和钨的炔烃配合物的合成和取代反应

  摘要：

  DOI：

  10.1021/om00138a037
• 作为产物：
  描述：

  草酰氯 、 Carbon monoxide;molybdenum;phenylmethanone;tetramethylazanium 在 pyridine 作用下， 以 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  三和四（亚磷酸三甲酯）取代的铬，钼和钨的炔烃配合物的合成和取代反应

  摘要：

  DOI：

  10.1021/om00138a037

文献信息

• Synthesis, crystal structures and spectroscopic properties of cationic carbyne complexes of molybdenum and tungsten supported by tripodal nitrogen, phosphorus and sulphur donor ligands
  作者：Fu-Wa Lee、Michael Chi-Wang Chan、Kung-Kai Cheung、Chi-Ming Che

  DOI：10.1016/s0022-328x(98)00564-6

  日期：1998.7

  Reaction of the tridentate ligands HCpy3 or Ppy3 (py=2-pyridyl) with Cl(CO)2py2MCPh (M=Mo, W) in THF at elevated temperature followed by metathesis with NaBPh4 in CH3CN affords [(η3-Xpy3)(CO)2MCPh]+ (M=W, X=P (2), HC (3); M=Mo, X=P (4)) in high yield. Interaction between 1,1,1-tris(diphenylphosphinomethyl)ethane (CH3C(CH2PPh2)3) or 1,4,7-trithiacyclononane (TTCN) and Cl(CO)2py2WCPh in the presence

  三齿的配体反应HCPy 3或聚吡咯3（PY = 2-吡啶基）被Cl（CO）2 PY 2 MCPh（M =钼，钨）在THF中在升高的温度下，然后通过复分解与NaBPh 4在CH 3 CN得到[（η 3 -Xpy 3）（CO）2 MCPh] +（M = W，X = P（2），HC（3）; M =钼，X = P（4））以高收率。1,1,1-三（二苯基膦甲基）乙烷（CH 3 C（CH 2 PPh 2）3）或1,4,7-三硫代环壬烷（TTCN）与Cl（CO）2的相互作用PY 2 WCPh在AgPF的存在6在回流的CH 3 CN给出[CH 3 C（CH 2 PPH 2）3 }（CO）2 WCPh] PF 6（5）和[（TTCN）（CO ）2 WCPh] PF 6（6），分别。这些络合物在320–340 nm处显示出很强的吸收带，而在400–500 nm区域中显示出较弱的吸收，而在330 n
• Carbyne complexes of the group 6 metals containing 1,4,7-triazacyclononane and its 1,4,7-trimethyl derivative
  作者：Fu-Wa Lee、Michael Chi-Wang Chan、Kung-Kai Cheung、Chi-Ming Che

  DOI：10.1016/s0022-328x(97)00578-0

  日期：1998.2

  Interaction of Cl(CO)(2)py(2)M=CPh (M=Mo, W) with 1,4,7-trimethyl-1,4,7-triazacyclononane (Me(3)TACN) in THF, followed by metathesis using NaBPh4 in aqueous medium, readily afford [(Me(3)TACN)M(CO)(2)(=CPh)]BPh4 (M=Mo (1a), W (2)). [(TACN)Mo(CO)(2)(=CPh)]BPh4 (1b) is similarly prepared using the molybdenum precursor and 1,4,7-triazacyclononane (TACN). Complex 1a, 1b and 2 are stable in the presence of concentrated hydrochloric acid at room temperature. The crystal structures of la and 2 both show that the three nitrogen atoms of Me(3)TACN are not equidistant from the metal centre as a consequence of the different trans influences of the carbyne and carbonyl groups. Complexes 1a, 1b and 2 exhibit intense absorption bands at 320-340 nm and weak absorptions in the 400-500 nm region, while excitation of 2 at 330 nm in acetonitrile gives an emission at 630 nm with a lifetime of 83 ns (Phi(em) = 1.6 X 10(-4)) at room temperature. The cyclic voltammograms of 1a and 2 in acetonitrile consist of a quasi-reversible couple (-2.15 V vs. Cp2Fe0/+) acid an irreversible wave (+0.77 V vs. Cp2Fe0/+). Both couples are assigned to ligand-centred processes. Reaction of Me(3)TACN with Cl(CO)(2)py(2)Cr=CPh in THF resulted in cleavage of the carbyne moiety to yield a binuclear product. (C) 1998 Elsevier Science S.A.