diiodo-2κ(2)I(3-methylpyridine-1κN)-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)O,N,N',O';2.kappa(2)O,O'-copper(II)zinc(II) | 228549-22-2

• 英文名称: diiodo-2κ(2)I(3-methylpyridine-1κN)-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)O,N,N',O';2.kappa(2)O,O'-copper(II)zinc(II)
• 英文别名: ([μ-bis(salicylidene)-1,3-propanediaminato](3-methylpyridine)copper(II))diiodozinc(II)
• CAS: 228549-22-2
• 化学式: C₂₃H₂₃CuI₂N₃O₂Zn
• 分子量: 756.2
• InChiKey: QBLCXXHKONWJFA-VSXIBYRUSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  3-甲基吡啶 、 copper(II) choride dihydrate 、 N,N'-二亚水杨基-1,3-二氨基丙烷 、 zinc(II) iodide 在 NH₃ 作用下， 以 1,4-二氧六环 、 甲醇 为溶剂， 生成 diiodo-2κ(2)I(3-methylpyridine-1κN)-μ-(2,2'-[1,3-propanediylbis(nitrilomethylidyne)]diphenolato)-1κ(4)O,N,N',O';2.kappa(2)O,O'-copper(II)zinc(II)
  参考文献：
  名称：

  {[μ-Bis(salicylidene)-1,3-propanediaminato]-(3-methylpyridine)copper(II)}diiodozinc(II)

  摘要：

  The title complex, [CuZnI2(C17H16N2O2)(C6H7N), consists of a doubly oxygen-bridged heteronuclear dimeric complex. The Cu atom has a distorted square-pyramidal environment involving two O atoms and two N atoms of the bis(salicylidene)-l,3-propanediaminate (SALPD(2)-) ligand, and an N atom of the 3-methylpyridine group. The Cu-O distances in the coordination plane are 1.973 (3) and 1.974(2)Angstrom, and the average Cu-N distance is 2.088 (4) Angstrom. In the bridging plane, the Cu-O-Zn, O-Zn-O, Zn-O-Cu and O-Cu-O angles are 102.5(1), 76.7(1), 102.7(1) and 77.9(1)degrees, respectively. The dihedral angle between the coordination plane around the Cu atom and the 3-melhylpyridine group is 88.4(1)degrees. The Cu Zn distance is 3.1013 (7) Angstrom.

  DOI：

  10.1107/s0108270199003273