[Tm(η5-3,5-di-tert-butyl-1,2,4-triphospholyl)2(η2-3,5-di-tert-butyl-1,2,4-triphospholyl)] | 1042435-43-7

• 英文名称: [Tm(η5-3,5-di-tert-butyl-1,2,4-triphospholyl)2(η2-3,5-di-tert-butyl-1,2,4-triphospholyl)]
• CAS: 1042435-43-7
• 化学式: C₃₀H₅₄P₉Tm
• 分子量: 862.457
• InChiKey: QQVWYPDGTNTPEA-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  碘化铥(III) 、 potassium 3,5-di-tert-butyl-1,2,4-triphosphacyclopentadienyl 以 均三甲苯 为溶剂， 以21%的产率得到[Tm(η5-3,5-di-tert-butyl-1,2,4-triphospholyl)2(η2-3,5-di-tert-butyl-1,2,4-triphospholyl)]
  参考文献：
  名称：

  Synthesis and structural characterisation of lanthanide and actinide phosphaorganometallic complexes derived from the 3,5-di-tert-butyl-1,2,4-triphospholyl ring anion, P3C2But−2: Crystal and molecular structures of [M(η5-P3C2But2)2(η2-P3C2But2)] (M=Sc, Y, Tm, and U)

  摘要：

  Treatment of MI3 ( M = Sc, Y, Tm, and U) with three equivalents of KP3C2Bu2t in refluxing toluene led to the corresponding monomeric, formally eight coordinate, complexes [M(eta(5)-P3C2Bu2t)(2)(eta(2)-P3C2Bu2t)] in moderate yields. In the solid state the complexes, which are all iso-structural, display an interesting assembly of ligands comprising of one eta(2)-(bent) and two eta(5)-ligated triphospholyl rings. NMR studies indicate that the complexes are fluxional in solution. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.03.030