| 193606-31-4

• CAS: 193606-31-4
• 化学式: C₃₀H₂₂Cl₂CuN₆O₆
• 分子量: 696.993
• InChiKey: LUFGNOSSPAAHOD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 硝西泮 以 丙酮 为溶剂， 以72%的产率得到
  参考文献：
  名称：

  IR and ESR study of Cu(II)-nitrazepam complexes

  摘要：

  The CuL2X2 (L = 7-nitro-1,3-dihydro-5-phenyl-2H-1,4-benzodiazepin-2-one, known as nitrazepam, X = Cl, Br) complexes were prepared and investigated by IR, ESR and magnetic susceptibility measurements. The IR spectra suggest that the Cu(II) ion is coordinated by two nitrogen and two halogen atoms; The powder ESR spectrum at room temperature of CUL2Br2 is quasiisotropic, while that of CuL2Cl2 is characteristic of an axial monomeric species with small rhombic distortions. The isotropic ESR spectra of these compounds in DMF and Py solutions suggest the presence of pseudo-tetrahedral monomeric species. Two different monomeric species were evidenced in Cu(II)-nitrazepam solutions adsorbed onto NaY zeolite. (C) 1997 Elsevier Science B.V.

  DOI：

  10.1016/s0022-2860(96)09633-0