| 743438-74-6

• CAS: 743438-74-6
• 化学式: C₂₈H₂₃Fe₂NO
• 分子量: 501.191
• InChiKey: VRPUYNDGTBBSCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 水 、 N-<1-oxo-2-(2-pyridyl)ethyl>pyridinium iodide 在 NaOH 、 ammonium acetate 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Towards the development of polynuclear electron reservoirs containing terpyridine metal complexes

  摘要：

  The preparations of multinuclear supramolecules assembled from 1',1"'-bis(terpyridyl)biferrocene redox-active subunit with Ru(II) metal centers are described. The appreciable variations detected in the Fe2+/Fe3+ oxidation potentials indicate that there is an interaction between the spacer and terminal ferrocenyl moieties. The binuclear bis(terpyridyl)biferrocene appears to be promising bridge which can ensure fast and quantitative transfer of energy within the array. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.03.018
• 作为产物：
  描述：

  2-乙酰基吡啶 、 1'-醛基联二茂铁 在 NaOH 作用下， 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Towards the development of polynuclear electron reservoirs containing terpyridine metal complexes

  摘要：

  The preparations of multinuclear supramolecules assembled from 1',1"'-bis(terpyridyl)biferrocene redox-active subunit with Ru(II) metal centers are described. The appreciable variations detected in the Fe2+/Fe3+ oxidation potentials indicate that there is an interaction between the spacer and terminal ferrocenyl moieties. The binuclear bis(terpyridyl)biferrocene appears to be promising bridge which can ensure fast and quantitative transfer of energy within the array. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.03.018

文献信息

• Development of Polynuclear Molecular Wires Containing Ruthenium(II) Terpyridine Complexes
  作者：Teng-Yuan Dong、Mei-ching Lin、Michael Yen-Nan Chiang、Jing-Yun Wu

  DOI：10.1021/om0497386

  日期：2004.8.1

  The preparations of multinuclear supramolecules assembled from 1',1'''-bis(terpyridyl)-biferrocene redox-active subunits with Ru2+ metal centers are described. The electrochemical measurements of the series of Ru2+-coordinated 1',1"'-bis(terpyridyl)biferrocene complexes are dominated by the Ru2+/Ru3+ redox couple (E-1/2 at similar to1.35 V), Fe2+/Fe3+ redox couples (E(1/)2 from similar to0.4 to similar to0.9 V), and terpy/terpy(-)herpy(2-) redox couples (E-1/2 at similar to-1.2 and similar to-1.4 V). The appreciable variations detected in the Fe2+/Fe3+ oxidation potentials indicate that there is an interaction between the spacer and the Ru2+ metal centers. On the coordination of Ru2+ metal centers with 1',1"'-bis(terpyridyl)biferrocene, there is a rise to a red-shifted and more intense (1)[(d(pi)(Fe))(6)] --> (1)[d(pi)(Fe))(5)(pi*(Ru)(terp))(1)] transition in the visible region. The observed red-shifted absorption from similar to510 nm in monomeric [Ru(terpy)(2)](2+) and [Ru(terpy)(fcterpy)](2+) complexes to similar to570 nm in polynuclear Ru2+ 1',1'''-bis(terpyridyl)biferrocene complexes reveals that there is a qualitative electronic coupling within the array. The coordination of Ru2+ transition-metal centers lowers the energy of the pi*(terpy) orbitals, giving a more red-shifted transition.