bis[[(dimethylsulfoxide-κO)-μ-N,N'-bis(salicylidene)-1,3-propandiaminatocopper(II)](azido)-(μ-azido-1:1)copper(II)] | 534568-33-7

• 英文名称: bis[[(dimethylsulfoxide-κO)-μ-N,N'-bis(salicylidene)-1,3-propandiaminatocopper(II)](azido)-(μ-azido-1:1)copper(II)]
• CAS: 534568-33-7
• 化学式: C₃₈H₄₄Cu₄N₁₆O₆S₂
• 分子量: 1139.19
• InChiKey: MYKQPQWHQGMSLN-STGPLLPMSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 二甲基亚砜 、 {copper(II)-(N,N'-disalicylidene-1,3-propanediamine)} 、 sodium azide 以 甲醇 、 水 、 二甲基亚砜 为溶剂， 以52%的产率得到bis[[(dimethylsulfoxide-κO)-μ-N,N'-bis(salicylidene)-1,3-propandiaminatocopper(II)](azido)-(μ-azido-1:1)copper(II)]
  参考文献：
  名称：

  Synthesis and Crystal Structure of Linear Chain Homotetranuclear Complexes with N₃ ⁻

  摘要：

  Mononuclear copper(II) complexes, Cu(L) [N,N'-bis(salicylidene)-1,3-propanediaminato]copper(II), and Cu(LDM) [N,N'-bis(salicylidene)2,2'-dimethyl-1,3-propanediaminato]copper(II), were prepared from the ONNO type ligands N,N'-bis(salicylidene)-1,3-diaminopropane (H2L) and N,N'-bis(salicylidene)-2,2'-dimethyl-1,3-diaminopropane (H2LDM). These mononuclear complexes were transformed into tetranuclear complexes, [(S)Cu(L)Cu(N-3)(2)](2) and [(S)Cu(LDM)Cu(N-3)(2)](2) (S are solvent molecules, DMSO, DMF, THF, dioxan), with N-3(-) and Cu(II) ions. All complexes were characterized by elemental analyses and IR spectroscopy. A molecular model of the complex [(DMSO)Cu(L)Cu(N-3)(2)] was obtained by single crystal x-ray diffraction methods.

  DOI：

  10.1081/sim-120017787