bis(4'-(4-pyridyl)-2,2':6':2''-terpyridine)ruthenium(II) monohexafluorophosphate mononitrate | 922493-12-7

• 英文名称: bis(4'-(4-pyridyl)-2,2':6':2''-terpyridine)ruthenium(II) monohexafluorophosphate mononitrate
• CAS: 922493-12-7
• 化学式: C₄₀H₂₈N₈Ru*F₆P*NO₃
• 分子量: 928.755
• InChiKey: SKOXQVCKCMLZPM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) nitrate hexahydrate 、 [Ru(4’-(4-pyridyl)-2,2’:6’,2’’-terpyridine)₂](PF₆)₂ 以 水 、 丙酮 为溶剂， 生成 bis(4'-(4-pyridyl)-2,2':6':2''-terpyridine)ruthenium(II) monohexafluorophosphate mononitrate
  参考文献：
  名称：

  Expanding the 4,4′-bipyridine ligand: Structural variation in {M(pytpy)2}2+ complexes (pytpy=4′-(4-pyridyl)-2,2′:6′,2″-terpyridine, M=Fe, Ni, Ru) and assembly of the hydrogen-bonded, one-dimensional polymer

  摘要：

  The solid state structures of [Ni(1)(2)][NO3](2) center dot 2MeOH center dot 2H(2)O, [Fe(1)(2)][ClO4](2) center dot 2MeOH center dot 0.5H(2)O, [Ru(1)(2)][PF6](2) and [Ru(1)(2)][PF6] [NO3] (1 = 4 '-(4-pyridyl)-2,2 ':6 ',2 ''-terpyridine) are presented and the structural variation observed for the {M(1)(2)}(2+) unit is discussed. Protonation of the pendant pyridine group in [Ru(1)(2)](2+) leads to the formation of a hydrogen-bonded, one-dimensional polymer [{Ru(1)(H1)}(n)](3n+) exemplifed by the solid-state structure of [{Ru(1)(H1)}{Fe(NCS)(6)} center dot 1.25H(2)O](n). (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.10.040