carbonyl(2,6-diphenylpyridinate(2-))platinum(II) | 263755-55-1

• 英文名称: carbonyl(2,6-diphenylpyridinate(2-))platinum(II)
• 英文别名: carbonyl[2,6-diphenylpyridyl-2,2'-ido]platinum；[(2,6-diphenylpyridine)Pt(CO)]
• CAS: 263755-55-1
• 化学式: C₁₈H₁₁NOPt
• 分子量: 452.371
• InChiKey: JTKCYVAGKXAJGD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  carbonyl(2,6-diphenylpyridinate(2-))platinum(II) 、 以 氘代氯仿 为溶剂， 生成
  参考文献：
  名称：

  The New Di-Gold Metallotweezer Based on an Alkynylpyridine System

  摘要：

  我们开发了一种简单的方法来制备一种金基金属镊子，它具有两个平面金-苯乙烯-NHC臂，由一个 2,6-双（3-乙炔基-5-叔丁基苯基）吡啶单元结合。这种金属镊子能够通过多芳香族客体与 NHC 配体的芘分子之间的 π-堆叠相互作用结合一系列多环芳香烃。金属镊子还被用作封装平面金属配合物的宿主，例如金（III）配合物[Au(C^N^C)(C≡CC6H4-OCH3-p)]，其结合常数高达 946 M-1。

  DOI：

  10.3390/molecules27123699
• 作为产物：
  描述：

  [Pt(2,6-diphenylpyridinate-H)(μ-Cl)]₂ 以 二甲基亚砜 、 N,N-二甲基甲酰胺 为溶剂， 生成 carbonyl(2,6-diphenylpyridinate(2-))platinum(II)
  参考文献：
  名称：

  C−H Activation Induced by Water. Monocyclometalated to Dicyclometalated:  C∧N∧C Tridentate Platinum Complexes

  摘要：

  Metalation of 2,6-diphenylpyridine (1) by potassium tetrachloroplatinate in acetic acid gives a monocyclometalated chloride-bridged dimer 4. This dimer is split with CO to give a kinetic product st with the incoming CO trans to the orthometalated carbon. The kinetic product of cleavage is shown to be 16 kJ mol(-1) higher in energy than the thermodynamic product 9c, which has the CO trans to the pyridine nitrogen. The isomerization of 9t to 9c is shown not to take place via an associative mechanism and, with analogue 11, is effectively suppressed when excess chloride is added, implying that it takes place via a chloride dissociation. The monocyclometalated 9 undergoes a second cyclometalation to give the C boolean AND N boolean AND C dicyclometalated complex 15 in high yield. This second cyclometalation is brought about by the simple expedient of adding water to the monocyclometalated precursor. The addition of water is rationalized on the basis of needing to ionize the HCl byproduct of the reaction. Using a substituted pyridine (5) analogous chemistry is observed. Single-crystal X-ray structures of one of the intermediates (6) and one of the final products (15) have been solved. Density functional theory calculations are used to rationalize the isomerizations of the monocyclometalated intermediates and the need to ionize HCl in the second cyclometalation.

  DOI：

  10.1021/om9910423

文献信息

• Molecular Recognition – Allosterism Generated by Weak Host–Guest Interactions in Molecular Rectangles
  作者：James D. Crowley、Ian M. Steele、Brice Bosnich

  DOI：10.1002/ejic.200500393

  日期：2005.10

  Two metal-based molecular rectangles that bear two identical binding sites form 1:2 host–guest adducts with a pair of analogous planar Pt2+ complexes. The larger of the two guests shows no binding allosterism with either of the two rectangles, but substantial positive allosterism is observed when the smaller guest binds to the rectangles. It is proposed that the smaller guest is better accommodated

  带有两个相同结合位点的两个基于金属的分子矩形与一对类似的平面 Pt2+ 配合物形成 1:2 的主客体加合物。两个客体中较大的客体与两个矩形中的任何一个均未表现出结合变构，但当较小客体与矩形结合时，观察到显着的正变构。建议较小的客体更好地容纳在受体的结合位点中，这会导致变构。各种实验，包括 1H NOESY 光谱，都支持较小的客体更好地嵌入受体的假设。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)
• Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers
  作者：Susana Ibáñez、Cristian Vicent、Eduardo Peris

  DOI：10.1002/anie.202112513

  日期：2022.1.10

  molecule in solution, in the gas phase and in the solid state. The behavior of the tert-butyl substituted tweezer differs greatly form that shown by the tweezer lacking of these bulky groups, whose dimeric structure is in equilibrium with the monomeric structure, therefore not showing any mechanical coercion that avoids the disassembly of the self-aggregated structure.

  在这项研究中，我们报告了一种新的机械互锁分子的制备，该分子由两个金属镊子的自聚集形成，该分子由两个芘-咪唑亚基金 (I) 臂和一个以吡啶为中心的五环双炔基接头组成。该分子的机械互锁性质源于连接到镊子臂芘部分侧面的庞大叔丁基基团的存在，这些叔丁基基团充当塞子，避免自聚集的金属镊子二聚体一旦被解离形成。通过结合实验技术，我们能够确认该分子在溶液、气相和固态中的机械互锁性质。叔丁基取代的镊子的行为与缺少这些大基团的镊子所显示的形式大不相同，
• Supramolecular Recognition Forces:  An Examination of Weak Metal−Metal Interactions in Host−Guest Formation
  作者：James D. Crowley、Ian M. Steele、B. Bosnich

  DOI：10.1021/ic0481531

  日期：2005.5.1

  Molecular receptors consisting of two parallel-disposed terpy-M-Cl units (M = Pd2+, Pt2+) are used to form host-guest adducts with aromatic molecules and with neutral square-planar Pt2+ complexes. Host-guest formation is controlled by several factors including pi-pi interactions and, in some cases, weak Pt-Pt interactions between the host and the guest. This latter interaction was examined by comparing the host-guest stability of adducts formed by isoelectronic Pt2- and Au3+ complexes with the Pt2+ receptor. Consistently, the former is more stable.
• Synthesis and Photophysical Properties of a Series of Biscyclometalated Platinum(II) Complexes on the Basis of a Tridentate 2,6-Diphenylpyridine
  作者：M. V. Kulikova、K. P. Balashev、Kh. Erzin

  DOI：10.1023/b:rugc.0000025140.64970.10

  日期：2003.12

  The complexes C,C-trans-[Pt(C<^>N<^>C)L](z) [C<^>N<^>C is bisdeprotonated 2,6-diphenylpyridinate (dppy(2-)); L = CO, Me2SO (dmso), ethylenediamine (en), CN-, pyrazine (pz), P(C6F5)(3), 4,4'-bipyridine (4,4'-bpy)] were synthesized and characterized by H-1 NMR, electronic, and emission spectroscopy. Spectral-luminescence properties of the chromophoric group (platinum-cyclometalating ligand) in the CC-trans-biscyclometalated complexes depend on the nature of the noncyclometalating ligand L, which is explained by its donor-acceptor effects on the form of existence of the complex in solution.
• ——
  作者：M. V. Kulikova、T. V. Taraskina、E. A. Cherezova、K. P. Balashev

  DOI：10.1023/a:1026159608823

  日期：——