[CpRh(μ-η5:η6-C4H4BPh)Rh(cod)][BF4] | 1021428-82-9

• 英文名称: [CpRh(μ-η5:η6-C4H4BPh)Rh(cod)][BF4]
• CAS: 1021428-82-9
• 化学式: BF₄*C₂₃H₂₆BRh₂
• 分子量: 605.886
• InChiKey: MODUCYDURYMCHA-NSNKXZTFSA-N

反应信息

• 作为产物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 Ag(dioxane)3BF4 、 (η5-cyclopentadienyl)(η5-1-phenylborole)rhodium 以 四氢呋喃 为溶剂， 以83%的产率得到[CpRh(μ-η5:η6-C4H4BPh)Rh(cod)][BF4]
  参考文献：
  名称：

  Reactions of the borole complex CpRh(η5-C4H4BPh) with monocationic organometallic fragments

  摘要：

  The B-phenylborole complex CpRh(eta(5)-C4H4BPh) (1) reacts with [ML](+) fragments to give the arene-type cationic complexes [CpRh(mu-eta(5):eta(6)-C4H4BPh) ML](+) (ML = RuCp* (3), Co(C4Me4) (4), Rh(cod) (5), and Ir(cod) (6)). Cation 4 undergoes a reversible rearrangement into the triple-decker complex [CpRh(mu-eta(5):eta(5)-C4H4BPh) Co(C4Me4)](+) (7) under visible light irradiation in CH2Cl2 solution. DFT calculations revealed greater stability of arene-type complexes over triple-decker isomers. The structure of [3] BF4 was determined by X-ray diffraction. (C) 2007 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2006.12.045