[(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe(CO)][PF6] | 88251-02-9

• 英文名称: [(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe(CO)][PF6]
• CAS: 88251-02-9
• 化学式: C₃₇H₃₉FeOP₂*F₆P
• 分子量: 762.475
• InChiKey: YRCLQFHIRADGKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe(CO)][PF6] 在 氢化钾 作用下， 以 四氢呋喃 为溶剂， 生成 五甲基环戊二烯基二羰基铁二聚物
  参考文献：
  名称：

  Lapinte, Claude; Catheline, Daniel; Astruc, Didier, Organometallics, 1984, vol. 3, # 5, p. 817 - 819

  摘要：

  DOI：
• 作为产物：
  描述：

  在 CO 作用下， 以 1,2-二氯乙烷 为溶剂， 以90%的产率得到[(η2-Ph2PCH2CH2PPh2)(η5-C5Me5)Fe(CO)][PF6]
  参考文献：
  名称：

  钢琴凳（五甲基环戊二烯基）铁配合物：合成与简单配位化学

  摘要：

  DOI：

  10.1021/om00085a022

文献信息

• Preparation and hydride reduction of the electron-rich cations [(Me5C5)Fe(CO)2L]+ (L = CO, PPh3, PMe3) and [(Me5C5)Fe(CO)(Ph2PCH2CH2PPh2)]+
  作者：Stephen G. Davies、Stephen J. Simpson、Susan E. Thomas

  DOI：10.1016/s0022-328x(00)99115-0

  日期：1983.9

  [(Me5C5)Fe(CO)2L]+ (3, L = PPh3; 4, L = PMe3) and [(Me5C5)Fe(CO)(Ph2PCH2CH2PPh2)]+ (5) have been prepared from [(Me5C5)Fe(CO)3]+ (2) by controlled decarbonylation reactions. Hydride reduction of these cations occurs at CO to give (Me5C5)Fe(CO)2H from 2 and 3, and [(Me5C5)Fe(CO)H]2(Ph2PCH2CH2PPh2) from 5, while complete reduction of carbon monoxide to the methyl complex (Me5C5)Fe(CO)-(PMe3)Me is observed

  阳离子[（Me 5 C 5）Fe（CO）2 L] +（3，L = PPh 3 ; 4，L = PMe 3）和[（Me 5 C 5）Fe（CO）（Ph 2 PCH 2 CH通过控制脱羰反应由[（Me 5 C 5）Fe（CO）3 ] +（2）制备2 PPh 2）] +（5）。这些阳离子的氢化物还原反应在CO处产生，从2和3得到（Me 5 C 5）Fe（CO）2 H，而[（Me 5 C 5）Fe（CO）H] 2（Ph 2 PCH 2 CH 2 PPh 2）从5开始，同时观察到一氧化碳完全还原为甲基络合物（Me 5 C 5）Fe（CO）-（PMe 3）Me阳离子4。
• Photochemical synthesis, reactivity, and electrochemical properties of [CpFeP2L]+ cations; (Cp = C5H5, C5Me5; L = Co vs. CH3CN; P = phosphine or phosphite)
  作者：Jaime Ruiz、Enrique Roman、Didier Astruc

  DOI：10.1016/0022-328x(87)85034-9

  日期：1987.3

  anthracene) is present and leads to Cp★Fe+P(OMe3)}3. Photoextrusion of one phosphite ligand from [C5R5FeP(OMe)3}3]+ (R = H, Me) or of the carbonyl from [C5R5Fe(P ⌢ P)(CO)]+ (R = H, Me; P ⌢ P = dppm, dppe) in CH3CN leads to CH3CN complexes which are reversibly oxidized.

  仅在存在敏化剂（丙酮或蒽）且有（例如）丙酮和蒽的情况下，才可能用P（OMe）3配体光解取代阳离子[Cp ★ Fe（对二甲苯）] +（Cp ★ = C 5 Me 5）导致Cp ★ Fe + P（OMe 3）} 3。来自[C 5 R 5 Fe P（OMe）3 } 3 ] +（R = H，Me）的一种亚磷酸酯配体或来自[C 5 R 5 Fe（P⌢P）（CO）] +的羰基的光挤出CH 3 CN中的（R = H，Me;P⌢P = dppm，dppe）导致CH 3 CN络合物被可逆氧化。
• One-Pot Synthesis of Mononuclear Iron Alkynyl Complexes by Photolysis
  作者：Gilles Argouarch、Guillaume Grelaud、Frédéric Paul

  DOI：10.1021/om100665u

  日期：2010.10.11

  A new access to organoiron complexes of type (dppe)Cp*Fe-C C- Ar the easily prepared precursor (CO)(2)Cp*FeCl (5) is de.vcribed. This direct one-pot transformation realized upon UV irradiation is illustrated by various aromatic alkynes. A mechanism is also proposed for this reaction via the key intermediate[dppe)Cp*Fe(CO)][PF6](6).
• Thiolate-Bridged Nickel–Iron and Nickel–Ruthenium Complexes Relevant to the CO-Inhibited State of [NiFe]-Hydrogenase
  作者：Puhua Sun、Dawei Yang、Ying Li、Yahui Zhang、Linan Su、Baomin Wang、Jingping Qu

  DOI：10.1021/acs.organomet.5b01035

  日期：2016.3.14

  By employing S(CH2CH2S )(2) (tpdt) and O(CH2CH2S )(2) (opdt) as bridging ligands, two nickeliron and two nickelruthenium heterodimetallic complexes, [Cp*M(-1(3)SSS?:2(2)SS-tpdt)Ni(dppe)][PF6] (1, M = Fe; 3, M = Ru) and [Cp*M(-1 kappa(SSO)-S-3:2 kappa(SS)-S-2-opdt)Ni(dppe)][PF6] (2, M = Fe; 4, M = Ru) (Cp* = eta(5)-C5Me5; dppe = Ph2P(CH2)(2)PPh2), were obtained by a one-pot synthetic method and were identified by spectroscopy and X-ray crystallography. At 1 atm of CO, the pendant oxygen atom dissociated from the iron or ruthenium center and rapidly transferred to the nickel center when a CO molecule attacked the iron or ruthenium center in 2 and 4. However, there was no similar reaction occurring in 1 and 3 with the pendant sulfur atom. We confirmed the solid-state structure of the CO complex [Cp*Fe(t-CO)(mu-1 kappa(SS)-S-2:2 kappa(SSO)-S-3-opdt)Ni(dppe)][PF6] (5), which represents a possible configuration in the CO-inhibited state of [NiFe]-hydrogenase and exhibits no catalytic activity in electrochemical proton reduction.