carbonyl-η-cyclopentadienyl(diphenylphosphino-N-phenylthioformimidato-P,S)iron | 80977-41-9

• 英文名称: carbonyl-η-cyclopentadienyl(diphenylphosphino-N-phenylthioformimidato-P,S)iron
• CAS: 80977-41-9
• 化学式: C₂₅H₂₀FeNOPS
• 分子量: 469.327
• InChiKey: IQRAPAHRNNVCBB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  dicarbonylcyclopentadienyliodoiron(II) 、 Trimethylsilyl-N-phenylthioamidodiphenylphosphin 以 四氢呋喃 为溶剂， 以85%的产率得到carbonyl-η-cyclopentadienyl(diphenylphosphino-N-phenylthioformimidato-P,S)iron
  参考文献：
  名称：

  Kunze, Udo; Antoniadis, Antonios, Zeitschrift fur Naturforschung, Teil B: Anorganische Chemie, Organische Chemie, 1981, vol. 36, # 12, p. 1588 - 1594

  摘要：

  DOI：

文献信息

• Synthesis, characterization and electrocatalytic H2 production of phosphine-substituted CpFe complexes
  作者：Jin-Ping Li、Su-Ping Luo、Shu-Zhong Zhan、Yao-Cheng Shi

  DOI：10.1016/j.poly.2018.06.009

  日期：2018.9

  Reaction of Ph2P(Se)CSNHPh with Cp2Fe2(CO)(4) in refluxing toluene affords complexes CpFe(CO)(k(2)P,S-Ph2PC(S)=NPh) (1) and CpFe(CO)(2)(kP-P(=Se)Ph-2) (2). Further, reactions of 2 with 1 equiv of PPh2R in the presence of Me3NO generate complexes CpFe(CO)(kSe-SeP(=Se)Ph-2)(L) (3, L = PPh3; 4, L = PPh2Py). Unlike 2, reactions of CpFe(CO)(2)(kP-P(=S)Ph-2) with PPh2R under the same conditions give the corresponding phosphine-substituted complexes CpFe(CO)(kp-p(=S)Ph-2)(L) (5, L= PPh3; 6, L = PPh2Py). All the new compounds have been characterized by elemental analyses, IR, H-1 NMR, C-13 NMR and P-31 NMR spectroscopy and structurally determined by X-ray crystallography. Electrochemical studies indicate that using HOAc or TFA as a proton source complexes 1-6 can catalyze H-2 evolution. (C) 2018 Published by Elsevier Ltd.