Mo(CO)5(phen) | 113704-90-8

• 英文名称: Mo(CO)5(phen)
• CAS: 113704-90-8
• 化学式: C₁₇H₈MoN₂O₅
• 分子量: 416.201
• InChiKey: OIIVNWNSSIVVKI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Mo(CO)5(phen) 以 四氢呋喃 为溶剂， 生成 钼,四羰基(1,10-亚铁试剂(邻二氮杂菲)-kN1,kN10)-,(OC-6-22)-
  参考文献：
  名称：

  Cao, Shibai; Shi, Yanlong; Hollmann, Jens, Journal of the Chemical Society, Dalton Transactions, 1996, p. 1629 - 1636

  摘要：

  DOI：

文献信息

• Laser Flash Photolysis Studies of Metal Carbonyls in Supercritical CO2 and Ethane
  作者：Qin Ji、Edward M. Eyring、Rudi van Eldik、Keith P. Johnston、Steven R. Goates、Milton L. Lee

  DOI：10.1021/j100036a021

  日期：1995.9

  The ring-closure reaction of M(CO)(5)L-L (M = W, Mo) where L-L denotes a bidentate ligand was chosen for its comparative independence of solvent properties to demonstrate the repulsive (or intrinsic) part of the activation volume. The ring-closure reaction rate constant was determined in supercritical CO2 and in supercritical ethane over the range between 1000 and 3500 psi at several temperatures (35, 42, 48, and 60 degrees C). The activation volume was observed to be as high as +7000 cm(3)/mol just above the critical point in each of these solvents. The ring-closure activation volume was also determined in liquid CO2 and in several other liquid solvents for comparison. These studies demonstrate a huge repulsive contribution to the activation volume in these two supercritical fluids.