(μ-tin)bis{dicarbonyl(η5-pentamethylcyclopentadienyl)manganese}(Mn-Mn) | 118018-15-8

• 英文名称: (μ-tin)bis{dicarbonyl(η5-pentamethylcyclopentadienyl)manganese}(Mn-Mn)
• CAS: 118018-15-8
• 化学式: C₂₄H₃₀Mn₂O₄Sn
• 分子量: 611.086
• InChiKey: JXEYOYMXJZTSCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  (μ-tin)bis{dicarbonyl(η5-pentamethylcyclopentadienyl)manganese}(Mn-Mn) 在 air 作用下， 以 四氢呋喃 为溶剂， 以52%的产率得到
  参考文献：
  名称：

  Metallorganische schutzgruppen für den aufbau ungewöhnlicher zinn-chalkogen-käfigverbindungen: Thiostannat(II) Sn3S42− und “Zinnoxidhydrat” Sn6(μ3-OH)4(μ3-O)4 als Liganden in RCp(CO)2Mn-Komplexen

  摘要：

  Thiostannates(II) are considered typical solid state compounds. Isolation of the thiostannate(II) Sn3S42- as a molecular entity is achieved by a priori protecting the tin building blocks with RCp(CO)2Mn moieties. The cubane-type (R)Cp(CO)2Mn-protected cage molecules [Na-[2,2,2]Kryptand][{(Cp*(CO)2MnSn)3S4}Na(THF)3] (1a) and [{(Cp(CO)2MnSn)3S4)Mn(THF)3] (1b) have been prepared and fully characterized. As an example of a (R)Cp(CO)2Mn protected rhombic dodecahedral cage molecule [(Cp*(CO)2Mn-Sn)6(mu3-O)4(mu3-OH)4] (2) has been obtained. X-Tay analysis of 2 shows that the Sn6(mu3-OH)4(mu3-O)4 cage of the formal ''tin-oxide-hydrate'', ''Sn3O3 . H2O'', acts as a ligand towards six Cp*(CO)2Mn units via the stereochemically active ''lone-pairs'' at the tin(II) centres.

  DOI：

  10.1016/0022-328x(93)80468-q
• 作为产物：
  描述：

  stannane 、 tricarbonyl(η5-pentamethylcyclopentadienyl)manganese 在 THF 作用下， 以 四氢呋喃 为溶剂， 以70%的产率得到(μ-tin)bis{dicarbonyl(η5-pentamethylcyclopentadienyl)manganese}(Mn-Mn)
  参考文献：
  名称：

  Herrmann, Wolfgang A.; Kneuper, Heinz-Josef; Herdtweck, Eberhardt, Chemische Berichte, 1989, vol. 122, p. 437 - 444

  摘要：

  DOI：

文献信息

• Herrmann, Wolfgang A., Angewandte Chemie, 1986, vol. 98, # 1, p. 57 - 77
  作者：Herrmann, Wolfgang A.

  DOI：——

  日期：——
• Trigonal-planar koordiniertes Sn0 in [{Cp′(CO)2Mn} 2SnHal]−:Zinnverbindungen vom “Iniden”-Typ
  作者：F. Ettel、G. Huttner、L. Zsolnai、C. Emmerich

  DOI：10.1016/0022-328x(91)83243-w

  日期：1991.8

  The hydride complexes Na.([L(CO)2Mn}2H]) (Na.1) (L = Cp, Cp', Cp star), react with tin halides Sn(Hal)2 to give dimanganastannacumulene compounds [L(CO)2Mn = Sn = Mn(CO)2L] (2). For L = Cp star the compound [Cp star(CO)2Mn = Sn = Mn(CO)2Cp star] (2a), which is already known, can be isolated. For L = Cp, Cp', 2 is only available in solution. In the presence of 2,2,2-Crypt, the cumulene intermediates 2 add the halide present in the solution forming the anionic ''inidene'' compounds [L(CO)2Mn Sn(Hal) Mn(CO)2L]- (4). For L = Cp' the compounds 4 (Hal = Cl (4a); Hal = Br (4b); Hal = I (4c)) are characterized by X-ray analyses. The compounds 4 show trigonal planar coordination around the bridging tin(0). Their geometry thus corresponds to the one observed at their isoelectronic neutral analogues with group 15 bridging elements [L(CO)2Mn...XR...Mn(CO)2L] (X = P, As, Sb, Bi). Synthesis and properties of the tin(0) complexes 4, as well as of tin(II) derivatives of type [L(CO)2Mn}Sn(SR)3]- (3) are presented and discussed with regard to spectroscopic and structural data.