[CdCl2(2,6-bis(benzimidazolyl)pyridine)]*DMF | 778596-12-6

• 英文名称: [CdCl2(2,6-bis(benzimidazolyl)pyridine)]*DMF
• 英文别名: [Cd(bbp)Cl2]*DMF
• CAS: 778596-12-6
• 化学式: C₃H₇NO*C₁₉H₁₃CdCl₂N₅
• 分子量: 567.756
• InChiKey: OSKGIDUNLHNNRD-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,6-双(2-苯并咪唑基)吡啶 、 N,N-二甲基甲酰胺 、 cadmium(II) chloride 以 甲醇 为溶剂， 以87.22%的产率得到[CdCl2(2,6-bis(benzimidazolyl)pyridine)]*DMF
  参考文献：
  名称：

  Syntheses, crystal structures of blue luminescent complexes based on 2,6-bis(benzimidazolyl) pyridine

  摘要：

  Two blue luminescent complexes, Cd(bbp)Cl-2 (1) and In(bbp)Cl-2(H20) (2) (bbp = 2, 6-bis(benzimidazolyl)pyridine) were synthesized and characterized by X-ray single crystal structure analyses. For complex 1: space group P2(1)/n, a = 14.491(3), b = 8.0147(19), c = 22.043(4) Angstrom, alpha = 90, beta = 117.71(11), gamma = 90degrees, V = 2266.3(9) Angstrom(3), Z = 4; for complex 2: space group P - 1, a = 7.075(3), b = 12.468(3), c = 14.418(3) alpha = 113.36(3) beta = 93.31(3), gamma = 90.45(3)degrees, V= 1165.0(7) Angstrom(3), Z = 2. Both complexes emit blue luminescence in solid state and DMF solution. Two emission peaks at 495 and 524 run are observed for complex 2 in DMF solution, the later can be assigned as metal-to-ligand charge transfer (MLCT) emission. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2004.07.006