| 1293409-76-3

• CAS: 1293409-76-3
• 化学式: C₂₅H₃₅ClNNiOP
• 分子量: 490.676
• InChiKey: ZFBIRUTYELTACE-SZQCDHDFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 氯二异丙基膦 、 2-chloro-3-[(2,6-diisopropyl-phenylimino)methyl]phenol 在 4-N,N-dimethylaminopyridine 作用下， 以 四氢呋喃 为溶剂， 以84%的产率得到
  参考文献：
  名称：

  Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes

  摘要：

  Two pincer-type nickel iminophosphinite complexes, [(2-(CH=NR)-6-(OPR'(2))C(6)H(3))NiCl) (R = 2,6-(i)Pr(2)C(6)H(3), R' = Ph (2a) or (i)Pr (2b)), were synthesized from the reactions of bis(1,5-cyclooctadiene)nickel(0) and corresponding iminophosphinite ligands. The solid state structures of the nickel pincer complexes were determined by X-ray single crystal diffraction studies. They were successfully employed in the Kumada reaction of non-activated aryl chlorides and phenylmagnesium bromide at room temperature. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.007
• 作为试剂：
  描述：

  对氯甲苯 、 苯基溴化镁 在 作用下， 以 四氢呋喃 为溶剂， 反应 18.0h， 生成 4,4'-二甲基联苯 、 4-甲基联苯
  参考文献：
  名称：

  Synthesis, characterization and application of pincer-type nickel iminophosphinite complexes

  摘要：

  Two pincer-type nickel iminophosphinite complexes, [(2-(CH=NR)-6-(OPR'(2))C(6)H(3))NiCl) (R = 2,6-(i)Pr(2)C(6)H(3), R' = Ph (2a) or (i)Pr (2b)), were synthesized from the reactions of bis(1,5-cyclooctadiene)nickel(0) and corresponding iminophosphinite ligands. The solid state structures of the nickel pincer complexes were determined by X-ray single crystal diffraction studies. They were successfully employed in the Kumada reaction of non-activated aryl chlorides and phenylmagnesium bromide at room temperature. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.01.007