1,4-bis(mer-trans-CH=CHRuCl(CO)(trimethylphosphane)3)-9,10-anthraquinone | 1279702-66-7

• 英文名称: 1,4-bis(mer-trans-CH=CHRuCl(CO)(trimethylphosphane)3)-9,10-anthraquinone
• CAS: 1279702-66-7
• 化学式: C₃₈H₆₄Cl₂O₄P₆Ru₂
• 分子量: 1043.81
• InChiKey: YIGHLSZJOADHIJ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 1,4-diethynyl-9,10-anthraquinone 、 三甲基膦 以 四氢呋喃 、 二氯甲烷 为溶剂， 以65%的产率得到1,4-bis(mer-trans-CH=CHRuCl(CO)(trimethylphosphane)3)-9,10-anthraquinone
  参考文献：
  名称：

  Synthesis, Characterization, and Electrochemical Properties of Diruthenium Complexes Bridged by Anthraquinones

  摘要：

  We have prepared four isomeric binuclear ruthenium complexes, in which two ruthenium units have been attached to the 1,4-(4a), 1,5- (4b), 1,8- (4c), or 2,6-positions (4d) of a central anthraquinone (Aq) moiety, leading to packed (4c) or extended (4a,b,d) topologies. All of these bimetallic complexes were fully characterized by elemental analysis, H-1, C-13{H-1}, and P-31 NMR{H-1} spectrometry, and UV/vis spectrophotometry. Moreover, the structures of 4a,b were established by X-ray crystallography. The electrochemical properties of the stable binuclear ruthenium complexes 4a-d were investigated, revealing that the two metal centers in 4a-c could interact with each other through an anthraquinone bridge, suggesting that the electron-withdrawing carbonyl chain actually functions as an effective bridge.

  DOI：

  10.1021/om100932u