CpMnFe2(μ-3-C=CHPh)(CO)8 | 208041-08-1

• 英文名称: CpMnFe2(μ-3-C=CHPh)(CO)8
• CAS: 208041-08-1
• 化学式: C₂₁H₁₁Fe₂MnO₈
• 分子量: 557.946
• InChiKey: JBQXNGLODKWKSK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  diiron nonacarbonyl 、 η(5)-cyclopentadienyl(phenylvinylidene)(dicarbonyl)manganese 以 正庚烷 为溶剂， 以10%的产率得到CpMnFe2(μ-3-C=CHPh)(CO)8
  参考文献：
  名称：

  Chemistry of vinylidene complexes

  摘要：

  The reaction of Cp(CO)(2)Mn=C=CHPh (1) with Pd(PPh3)(4) followed by the replacement of the PPh3 ligands by diphosphines Ph2P(CH2)(2)PPh2 (dppe) or Ph2P(CH2)(3)PPh2 (dppp) (where dppe is bis(diphenylphosphino)ethane and dppp is 1,3-bis(diphenylphosphino)propane) afforded the binuclear complexes Cp(CO)(2)MnPd(mu-C=CHPh)(dppe) (2a) and Cp(CO)(2)MnPd(mu-C=CHPh)(dppp) (2b), respectively. The reactions of 2a and 2b with Fe-2(CO)(9) gave the trinuclear complex CpMnFe2(mu(3)-C=CHPh)(CO)(8) (3). Competitive transmetallation took the second pathway to yield clusters containing the PdFe3 and PdFe2 cores. Complex 3 was also formed in the thermal reaction of compound 1 with Fe-2(CO)(9). Complex 3 was studied by IR spectroscopy, H-1 and C-13 NMR spectroscopy, mass spectrometry, and X-ray diffraction analysis.

  DOI：

  10.1007/bf02494788

文献信息

• Antonova; Ioganson; Deikhina, Russian Chemical Bulletin, 1998, vol. 47, # 3, p. 531 - 632
  作者：Antonova、Ioganson、Deikhina、Pogrebnyakov、Pavlenko、Rubailo、Generalova、Petrovskii、Dolgushin、Starikova、Yanovskii、Belokon'、Ginzburg

  DOI：——

  日期：——