| 1494579-48-4

• CAS: 1494579-48-4
• 化学式: C₂₄H₂₃ClN₅Pd*Cl
• 分子量: 558.806
• InChiKey: RVJVMNULEIHANC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  chloro(1,5-cyclooctadiene)rhodium(I) dimer 、 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  Evaluation of Multisite Polypyridyl Ligands as Platforms for the Synthesis of Rh/Zn, Rh/Pd, and Rh/Pt Heterometallic Complexes

  摘要：

  Ligands containing linked dipicolylamine (dpa) and bipyridine (bpy) sites have been utilized in the synthesis of monometallic and heterometallic complexes. The two sites have different selectivities for metal binding, which allows preferential formation of singly metalated complexes. The dpa site of the ligands has been observed to bind selectively to Zn2+, Pd2+, and Pt2+, while the bpy site binds selectively to Rh+. Addition of a second metal then results in the formation of heterometallic products. In the presence of CD3OD, the heterometallic Rh/Pt and Rh/Pd complexes undergo rapid selective H/D exchange of one of the diastereotopic protons of the dpa methylene group.

  DOI：

  10.1021/ic301810y
• 作为产物：
  描述：

  5 5'-二甲基-2,2'-二吡啶 在 N-溴代丁二酰亚胺(NBS) 、 偶氮二异丁腈 、 四丁基碘化铵 、 potassium carbonate 作用下， 以 四氢呋喃 、 甲醇 、 四氯化碳 为溶剂， 反应 34.0h， 生成
  参考文献：
  名称：

  Evaluation of Multisite Polypyridyl Ligands as Platforms for the Synthesis of Rh/Zn, Rh/Pd, and Rh/Pt Heterometallic Complexes

  摘要：

  Ligands containing linked dipicolylamine (dpa) and bipyridine (bpy) sites have been utilized in the synthesis of monometallic and heterometallic complexes. The two sites have different selectivities for metal binding, which allows preferential formation of singly metalated complexes. The dpa site of the ligands has been observed to bind selectively to Zn2+, Pd2+, and Pt2+, while the bpy site binds selectively to Rh+. Addition of a second metal then results in the formation of heterometallic products. In the presence of CD3OD, the heterometallic Rh/Pt and Rh/Pd complexes undergo rapid selective H/D exchange of one of the diastereotopic protons of the dpa methylene group.

  DOI：

  10.1021/ic301810y

文献信息

• Heterobimetallic Complexes of Polypyridyl Ligands Containing Paramagnetic Centers: Synthesis and Characterization by IR and EPR
  作者：Sarah K. Goforth、Richard C. Walroth、Joseph A. Brannaka、Alexander Angerhofer、Lisa McElwee-White

  DOI：10.1021/ic401952s

  日期：2013.12.16

  Ligands containing linked dipicolylamine (dpa) and bipyridine sites have been explored as platforms for the synthesis of heterometallic complexes containing the paramagnetic metals Cu2+ and Co2+. IR and EPR studies on the bimetallic complexes and simplified model compounds support dpa-selective binding by both of these metals. The IR spectra have also been compared to those of diamagnetic Rh+, Zn2+

  已经研究了包含连接的二聚烯丙基胺（dpa）和联吡啶位点的配体作为合成包含顺磁性金属Cu 2+和Co 2+的杂金属配合物的平台。对双金属配合物和简化模型化合物的IR和EPR研究支持这两种金属对dpa的选择性结合。还已将IR光谱与抗磁性Rh +，Zn 2+和Pd 2+络合物的光谱进行了比较，它们的金属结合位点已通过NMR技术独立确定。结合偏好已用于控制异金属Pt / Cu，Pd / Cu和Rh / Cu络合物合成中的选择性金属化。