[{Ni(N,N′-bis(salicylidene)-1,3-diaminopropane(2-))}₂Na(perchlorate)] | 1448795-73-0

• 英文名称: [{Ni(N,N′-bis(salicylidene)-1,3-diaminopropane(2-))}₂Na(perchlorate)]
• 英文别名: [{Ni(salpn)}₂Na(ClO₄)]
• CAS: 1448795-73-0
• 化学式: C₃₄H₃₂ClN₄NaNi₂O₈
• 分子量: 800.473
• InChiKey: JBNHFMUSQYFDJK-KZAXEWDKSA-I

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  sodium perchlorate monohydrate 、 nickel(II) perchlorate hexahydrate 、 N,N'-二亚水杨基-1,3-二氨基丙烷 以 甲醇 为溶剂， 反应 1.0h， 以75%的产率得到[{Ni(N,N′-bis(salicylidene)-1,3-diaminopropane(2-))}₂Na(perchlorate)]
  参考文献：
  名称：

  Sodium-mediated self-assembly of two nickel(II) Schiff base complexes: crystal structure and characterizations

  摘要：

  Sodium-assisted self-assembly of two nickel(II) Schiff base complexes under similar reaction conditions yield hetero-metallic compounds [{Ni(salpn)}(2)Na(ClO4)] (1) and [{Ni(salpr)}(3)Na][Ni(salpr)](2)ClO42H2O (2) (where salpn=N,N-bis-(salicylidene)-1,3-diaminopropane and salpr=N,N-bis-(salicylidene)-1,2-diaminopropane). Both have been characterized by physico-chemical techniques and single-crystal X-ray diffraction. Crystal structure reveals that in the tri-metallic system of 1 sodium is sandwiched between two [Ni(salpn)] units while the hexametallic system of 2 consists of tetrametallic cluster ion [{Ni(salpr)}(3)Na](+) with encapsulated sodium by three [Ni(salpr)] units. In both complexes, sodium adopts distorted trigonal prismatic geometry leaving nickel(II) in a distorted square-planar environment. Structural characterization also reveals that 2:1 (for 1) and 3:1 (for 2) self-assemblies of metallo-ligand and sodium were achieved with slight variation in ligand backbone.

  DOI：

  10.1080/00958972.2013.810731