[Cu2(2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline)2(2,5-pydc)2]·H2O | 1443446-26-1

• 英文名称: [Cu2(2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline)2(2,5-pydc)2]·H2O
• 英文别名: [Cu₂(2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline)₂(2,5-pydc)₂]·H₂O；[Cu₂(MOPIP)₂(2,5-pydc)₂]·H₂O
• CAS: 1443446-26-1
• 化学式: C₅₄H₃₅Cu₂N₁₀O₁₀*H₂O
• 分子量: 1129.04
• InChiKey: UUDLFNMUINHJLI-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline 、 2,5-二吡啶羧酸 、 copper(II) acetate monohydrate 在 sodium hydroxide 作用下， 以 水 为溶剂， 反应 120.0h， 以78%的产率得到[Cu2(2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline)2(2,5-pydc)2]·H2O
  参考文献：
  名称：

  Syntheses, structures, fluorescent properties and natural bond orbital analyses of metal–organic complexes based on 5,6-substituted 1,10-phenanthroline derivatives

  摘要：

  Six new metal-organic coordination complexes, [Cd(MEDPQ)(2,5-pydc)](n) (1), [Cd-2(MOPIP)(2)(2,5-pydc)(2)](n) (2), [Cu-2(MOPIP)(2)(2,5-pydc)(2)]center dot H2O (3), [Mn(MOPIP)(2)(2,5-pydc)]center dot 3H(2)O (4), [Cd(MOPIP)(2)(2,6-pydc)]center dot 3H(2)O (5) and [Cd-2(MOPIP)(2)(2,3-pydc)(2)center dot H2O](n) (6) (MEDPQ = 2-methyldipyrido[3,2-f:2',3'-h]quinoxaline, MOPIP = 2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, 2,5-H(2)pydc = pyridine-2,5-dicarboxylic acid, 2,6-H(2)pydc = pyridine-2,6-dicarboxylic acid, and 2,3-H(2)pydc = pyridine-2,3-dicarboxylic acid), have been prepared through hydrothermal reactions. The transformation of coordination modes of transition metal ions and organic carboxylate ligands has a crucial influence on the multinuclear structures of these series. In compounds 1 and 2, binuclear Cd(II) subunits occur, which are connected by 2,5-pydc anions to construct an undulating network. By selecting the different transition metal, ions, we get the compounds 3 and 4. For the compound 3, the Cu(II) centers are linked by 2,5-pydc ligands to form a binuclear dimer. Compound 4 shows a mononuclear compound. For complexes 5 and 6, by changing the dicarboxylate ligands, Cd(II) adopts a heptacoordinated mode to form a mononuclear compound and chain framework. In addition, fluorescent properties of 2-4 have been reported. (c) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.04.054