[(ruthenium)3(carbonyl)10(3,4-dimethylphenylphosphole)2] | 1401224-04-1

• 英文名称: [(ruthenium)3(carbonyl)10(3,4-dimethylphenylphosphole)2]
• CAS: 1401224-04-1
• 化学式: C₃₄H₂₆O₁₀P₂Ru₃
• 分子量: 959.732
• InChiKey: ONEMGGBZAFDMJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  十二羰基三钌 、 1-苯基-3,4-二甲基膦杂环戊二烯) 以 环己烷 为溶剂， 反应 0.67h， 以25%的产率得到[(ruthenium)3(carbonyl)11(3,4-dimethylphenylphosphole)]
  参考文献：
  名称：

  Insertion of a phospholide unit into a metal–metal bond: Synthesis and X-ray structure of [Ru3(CO)9(μ:η1:η5-PC4H2Me2)(η1-C6H5)]

  摘要：

  The reaction of [Ru-3(CO)(12)] with 3,4-dimethyl-1-phenylphosphole under mild conditions affords three derivatives which were identified by means of spectroscopic methods as the substitution compounds [Ru-3(CO)(12) (x)(PhPC4H2Me2)(x)] (x = 1, 2, 3) in which the phosphole ligand acts as a tertiary phosphine bonded through the phosphorus atom. Thermolysis of the monosubstituted [Ru-3(CO)(11)(PhPC4H2Me2)] in cyclohexane affords two new clusters, characterised as [Ru-3(CO)(9)(mu(3):eta(2):eta(2):eta(2)-PhPC4H2Me2)] and [Ru-3(CO)(9)(mu:eta(1):eta(5)-PC4H2Me2)(eta(1)-C6H5)], where the phosphole ring behaves as a six-and seven-electron donor ligand respectively. The reaction with [Os3H2(CO)(10)] gives the new species [Os-3(mu-H)(CO)(9)(mu(3):eta(1):eta(1):eta(2)-PhPC4H3Me2)] in which the ligand behaves as a five-electron donor. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.01.033