| 1438413-39-8

• CAS: 1438413-39-8
• 化学式: C₄H₈O*C₃₆H₃₁CuFeO₂P₂
• 分子量: 749.088
• InChiKey: YZGFSAYTAQMJNM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,1'-双(二苯基膦)二茂铁 、 copper (I) acetate 以 四氢呋喃 为溶剂， 反应 0.25h， 以85%的产率得到
  参考文献：
  名称：

  Copper Chalcogenide Clusters Stabilized with Ferrocene-Based Diphosphine Ligands

  摘要：

  The redox-active diphosphine ligand 1,1'-bis(diphenylphosphino)ferrocene (dppf) has been used to stabilize the copper(1) chalcogenide clusters [Cu-12(mu(4)-S)(6)(mu-dppf)(4)] (1), [Cu-8(mu(4)-Se)(4)(mu-dppf)(3)] (2), [Cu-4(mu(4)-Te) (mu(4)-eta(2)-Te-2)(mu-dppf)(2)] (3), and [Cu-12(mu(5)-Te)(4)(mu(8)-eta(2)-Te-2)(2)(mu-dppf)(4)] (4), prepared by the reaction of the copper(I) acetate coordination complex (dppf)CuOAc (5) with 0.5 equiv of E(SiMe3)(2) (E = S, Se, Te). Single-crystal X-ray analyses of complexes 1-4 confirm the presence of {Cu2xEx} cores stabilized by dppf ligands on their surfaces, where the bidentate ligands adopt bridging coordination modes. The redox chemistry of cluster 1 was examined using cyclic voltammetry and compared to the electrochemistry of the free ligand dppf and the corresponding copper(I) acetate coordination complex 5. Cluster 1 shows the expected consecutive oxidations of the ferrocene moieties, Cu-I centers, and phosphine of the dppf ligand.

  DOI：

  10.1021/ic3021854