[W(CO)₅{PC(Ph)C(Ph)}][AlCl₄] | 1418581-56-2

• 英文名称: [W(CO)₅{PC(Ph)C(Ph)}][AlCl₄]
• CAS: 1418581-56-2
• 化学式: AlCl₄*C₁₉H₁₀O₅PW
• 分子量: 701.903
• InChiKey: AQKSPLWJRWYYQM-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [W(CO)₅{PC(Ph)C(Ph)}][AlCl₄] 、 三苯基膦 以 二氯甲烷 为溶剂， 以43.6 mg的产率得到[W(CO)₅{P(PPh₃)C(Ph)C(Ph)}][AlCl₄]
  参考文献：
  名称：

  Facile Phosphorus–Carbon Bond Formation using a Tungsten-Coordinated Phosphirenyl Cation

  摘要：

  Reaction of K-2[W(CO)(5)] with Cl2PN-i-Pr-2 in the presence of diphenylacetylene leads to the tungsten aminophosphirene complex [W(CO)(5){P(N-i-Pr-2)C(Ph)C-(Ph)}] (1), which can be converted to the chlorophosphirene complex [W(CO)(5){P(Cl)C(Ph)C(Ph)}] (2) by reaction with HCl. Chloride abstraction from 2 with excess AlCl3 leads to the tungsten-complexed phosphirenyl cation [W(CO)(5){PC-(Ph)C(Ph)}][AlCl4] (3). Compound 3 reacts with PPh3 to form a phosphoniophosphirene complex and undergoes electrophilic aromatic substitution with ferrocene to form a ferrocenylphosphirene complex. Chloride abstraction from 2 with silver triflate leads to a phosphirenyl triflate complex, which reacts with PPh3 and ferrocene in the same fashion as 3 but also reacts cleanly with a wider range of substrates, including phenylacetylene and allyltrimethylsilane, to form respectively a phenyl-alkynylphosphirene complex and an allylphosphirene complex.

  DOI：

  10.1021/om301266x
• 作为产物：
  描述：

  dipotassium pentacarbonyltungstate(-II) 以 四氢呋喃 、 乙醚 、 二氯甲烷 为溶剂， 反应 2.5h， 生成 [W(CO)₅{PC(Ph)C(Ph)}][AlCl₄]
  参考文献：
  名称：

  Facile Phosphorus–Carbon Bond Formation using a Tungsten-Coordinated Phosphirenyl Cation

  摘要：

  Reaction of K-2[W(CO)(5)] with Cl2PN-i-Pr-2 in the presence of diphenylacetylene leads to the tungsten aminophosphirene complex [W(CO)(5){P(N-i-Pr-2)C(Ph)C-(Ph)}] (1), which can be converted to the chlorophosphirene complex [W(CO)(5){P(Cl)C(Ph)C(Ph)}] (2) by reaction with HCl. Chloride abstraction from 2 with excess AlCl3 leads to the tungsten-complexed phosphirenyl cation [W(CO)(5){PC-(Ph)C(Ph)}][AlCl4] (3). Compound 3 reacts with PPh3 to form a phosphoniophosphirene complex and undergoes electrophilic aromatic substitution with ferrocene to form a ferrocenylphosphirene complex. Chloride abstraction from 2 with silver triflate leads to a phosphirenyl triflate complex, which reacts with PPh3 and ferrocene in the same fashion as 3 but also reacts cleanly with a wider range of substrates, including phenylacetylene and allyltrimethylsilane, to form respectively a phenyl-alkynylphosphirene complex and an allylphosphirene complex.

  DOI：

  10.1021/om301266x