[W2(η5-cyclopentadienyl)2(μ-Cl)(μ-CO)(CO)2(μ-bis(diphenylphosphino)methane)]B(3,5-C6H3(CF3)2)4 | 501922-30-1

• 英文名称: [W2(η5-cyclopentadienyl)2(μ-Cl)(μ-CO)(CO)2(μ-bis(diphenylphosphino)methane)]B(3,5-C6H3(CF3)2)4
• CAS: 501922-30-1
• 化学式: C₃₂H₁₂BF₂₄*C₃₈H₃₂ClO₃P₂W₂
• 分子量: 1864.99
• InChiKey: QAERDIXHONRTOW-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [W2(η5-cyclopentadienyl)2(μ-CO)(CO)2(μ-bis(diphenylphosphino)methane)]B(3,5-C6H3(CF3)2)4 、 氯 以 二氯甲烷 为溶剂， 以85%的产率得到[W2(η5-cyclopentadienyl)2(μ-Cl)(μ-CO)(CO)2(μ-bis(diphenylphosphino)methane)]B(3,5-C6H3(CF3)2)4
  参考文献：
  名称：

  Chemistry of Highly Electrophilic Binuclear Cations. 2. Oxidation Reactions of [W₂(η⁵-C₅H₅)₂(CO)₄(μ-Ph₂PCH₂PPh₂)] with [FeCp₂][B{3,5-C₆H₃(CF₃)₂}₄]

  摘要：

  Chemical oxidation of the title compound [W2Cp2(CO)(4)(mu-dppm)] (Cp = eta(5)-C5H5; dppm = Ph2PCH2PPh2) with 1 equiv of [FeCp2](BAr4') (Ar' = 3,5-C6H3(CF3)(2)) leads to the tetracarbonyl radical [W2Cp2(CO)(4)(mu-dppm)](BAr4'), which experiences spontaneous decarbonylation to give the 31-electron radical [W2Cp2(mu-CO)(CO)(2)(mu-dppm)](BAr4'). Oxidation of [W2Cp2(CO)(4)(mu-dppm)] with 2 equiv of [FeCp2](BAr4') gives the tricarbonyl derivative [W2Cp2(mu-CO)(CO)(2)(mu-dppm)](BAr4')(2). The same result is obtained when oxidizing the radical [W2Cp2(mu-CO)(CO)(2)(mu-dppm)]-(BAr4') with [FeCp2](BAr4'). The triply bonded complex [W2Cp2(mu-CO)(CO)(2)(mu-dppm)](BAr4')(2), which displays fluxional behavior in solution, reacts with P(OMe)(3) to give [W2Cp2(mu-CO)(CO){P(OMe)(3)}(mu-dppm)](BAr4')(2), the structure of which has been solved through a single-crystal X-ray diffraction study. Reaction of [W2Cp2(mu-CO)(CO)(2)(mu-dppm)](BAr4')(2) with salts of halide ions X- (X = Cl, Br, I) gives the corresponding halo derivatives [W2Cp2(mu-X)(mu-CO)(CO)(2)(mu-dppm)] (BAr4'). When X = I, a mixture of two isomers differing in the relative positions of the bridging halide and carbonyl is obtained. The same halide compounds were obtained in the reactions of paramagnetic [W2Cp2(mu-CO)(CO2(mu-dppm)]-(BAr4') with halogens X-2. The tricarbonyl radical was found to react slowly with water to give the known hydroxycarbyne derivative [W2Cp2(mu-COH)(CO2(mu-dppm)](BAr4').

  DOI：

  10.1021/om020669+