cesium tetrafluorochlorate(III) | 15321-04-7

• 英文名称: cesium tetrafluorochlorate(III)
• CAS: 15321-04-7
• 化学式: ClF₄*Cs
• 分子量: 244.352
• InChiKey: SUWKJPYPDHZMIV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  cesium tetrafluorochlorate(III) 以 neat (no solvent) 为溶剂， 生成 cesium fluoride
  参考文献：
  名称：

  Popov, A. I.; Kiselev, Yu. M.; Sukhoverkhov, V. F., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 789 - 791

  摘要：

  DOI：
• 作为产物：
  描述：

  三氟化氯 、 caesium carbonate 以 neat (no solvent) 为溶剂， 生成 cesium tetrafluorochlorate(III)
  参考文献：
  名称：

  Popov, A. I.; Kiselev, Yu. M.; Sukhoverkhov, V. F., Russian Journal of Inorganic Chemistry, 1988, vol. 33, p. 789 - 791

  摘要：

  DOI：

文献信息

• The reaction of fluoroxidizers with rare earth elements, zirconium and hafnium oxides
  作者：M.N. Brechovskich、A.I. Popov、V.A. Fedorov、Yu.M. Kiselev

  DOI：10.1016/0025-5408(88)90266-8

  日期：1988.10

  Reactions between XeF2 or alkali metal tetrafluorohalogenates(III) and Rare Earth elements oxides, ZrO2, and HfO2 have been studied. The formation conditions of the binary and complex fluorides have been investigated. The comparison of the fluorination activity of Xe(II), Cl(III), and Br(III) fluorides has been proposed.

  已经研究了 XeF2 或碱金属四氟卤酸盐 (III) 与稀土元素氧化物、ZrO2 和 HfO2 之间的反应。研究了二元和复合氟化物的形成条件。已提议比较 Xe(II)、Cl(III) 和 Br(III) 氟化物的氟化活性。
• Synthesis and Characterization of the Tetrafluoridochlorates(III) <i>A</i> [ClF ₄ ] ( <i>A</i> = K, Rb, Cs)
  作者：Benjamin Scheibe、Sergei I. Ivlev、Antti J. Karttunen、Florian Kraus

  DOI：10.1002/ejic.202000106

  日期：2020.4.16

  Single-crystalline tetrafluoridochlorates(III) A[ClF4] (A = K, Rb, Cs) were synthesized from solvolysis reactions of alkali metal fluorides in liquid chlorine trifluoride. The structures were examined by means of single-crystal X-ray diffraction. K[ClF4] crystallizes in the K[BrF4] structure type, whereas the Rb and Cs compounds crystallize in the Li[AuF4] structure type.

  单晶四氟氯酸盐 (III) A[ClF4] (A = K, Rb, Cs) 是由碱金属氟化物在液态三氟化氯中的溶剂分解反应合成的。通过单晶X射线衍射检查结构。K[ClF4] 以 K[BrF4] 结构类型结晶，而 Rb 和 Cs 化合物以 Li[AuF4] 结构类型结晶。
• Syntheses and properties of FOIF4O, ClOIF4O, HOIF4O, and tetrafluoroperiodates
  作者：Karl O. Christe、Richard D. Wilson、Carl J. Schack

  DOI：10.1021/ic50221a034

  日期：1981.7
• Popov, A. I.; Sukhoverkhov, V. F.; Chumaevskii, N. A., Russian Journal of Inorganic Chemistry, 1990, vol. 35, p. 626 - 632
  作者：Popov, A. I.、Sukhoverkhov, V. F.、Chumaevskii, N. A.

  DOI：——

  日期：——
• Preparation and Structures of Salts with the Anions of IF2?, ClF4? IF4?, TeF7?, and AsF4?
  作者：Xiongzhi Zhang、Konrad Seppelt

  DOI：10.1002/zaac.19976230178

  日期：——

  AbstractSingle crystal structures are presented for the IF2−, ClF4−, IF4−, TeF7−, and AsF4− fluoroanions. The 1,1,3,3,5,5 hexamethylpiperidinium (pip+) ion was used as cation in order to obtain good crystallinity and to avoid twinning and disorder which are notorious with the tetramethylammonium ion. Precise structural data are obtained for the first time, and the ions have the expected geometries. The pip+ has the further advantage that cation‐anion interactions are weak, which results in fairly ideal structures of the anions. Pip+BrF2− is too unstable to be obtained in single crystal form, and pip+BrOF4− as well as NO+BrOF4− show disordered anions and cations.