[((Me3Si)2C5H3)2SmCl]2 | 81523-76-4

• 英文名称: [((Me3Si)2C5H3)2SmCl]2
• CAS: 81523-76-4
• 化学式: C₄₄H₈₄Cl₂Si₈Sm₂
• 分子量: 1209.46
• InChiKey: GXYWWUMLGNVKQI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  氯化钐 、 bis(trimethylsilyl)cyclopentadienyllithium 以 四氢呋喃 为溶剂， 以>40的产率得到[((Me3Si)2C5H3)2SmCl]2
  参考文献：
  名称：

  Use of the bis(trimethylsilyl)cyclopentadienyl ligand for stabilising early (f⁰–f³) lanthanocene chlorides; X-ray structure of [(Pr{η-[C₅H₃(SiMe₃)₂]}₂Cl)₂] and of isoleptic scandium and ytterbium complexes

  摘要：

  在四氢呋喃中，适当的MCl3与2Li-[C5H3(SiMe3)2]反应得到[M{η-[C5H3-(SiMe3)2]}2Cl)2](M = Sc、Y、La、Ce、Pr、Nd、Sm、Eu、Gd、Tb、Dy、Ho、Er、Tm、Yb或Lu)；第一个早期镧锆氯化物的X射线结构[(Pr{η-[C5H3-(SiMe3)2]}2Cl)2](Sc和Yb配合物是等结构的)显示Pr原子处于扭曲的四面体环境中，重要的分子参数包括Pr–Cl平均.. 2·81，Pr–C(η-)平均 2·76 Å，Pr … Pr' 4·372(1) Å，Cl–Pr–Cl' 78，Pr–Cl–Pr' 102 °。

  DOI：

  10.1039/c39810001190

文献信息

• Synthesis, Molecular Structure, and Reactivity of Organolanthanide Fluoride Complexes, [{(Me₃Si)₂C₅H₃}₂Ln(μ-F)]₂ (Ln = La, Nd, Sm, Gd) and [(C₅H₅)₂Ln(μ-F)(THF)]₂ (Ln = Y, Yb)
  作者：Zuowei Xie、Kwoli Chui、Qingchuan Yang、Thomas C. W. Mak、Jie Sun

  DOI：10.1021/om980162s

  日期：1998.8.1

  Treatment of Me3NHF with I equiv of [(Me3Si)(2)C5H3](3)Ln or (C5H5)(3)Ln in THF gave [-(Me3Si)(2)C5H3}(2)LnF](2) (Ln = La (1), Nd (2), Sm (3), Gd (4)) or [(C5H5)(2)LnF(THF)](2) (Ln = Y (5), Yb (6)) in moderate to good yield. All of them were fully characterized by elemental analyses, spectroscopy, and X-ray analyses. Compound 3 reacted with Na, AlCl3, (C6H5)(3)-SiOH, and 2,6-(Pr2C6H3OH)-C-i to form [(Me3Si)(2)C5H3](2)Sm(THF), [(Me3Si)(2)C5H3}(2)SmCl](2), [(C6H5)(3)SiO](3)Sm(THF)(3) (7), and [2,6-(Pr2C6H3O)-C-i](3)Sm(THF)(3) (8), respectively. The molecular structures of [(Me3Si)(2)C5H3}(2)SmCl](2), 7, and 8 were confirmed by X-ray diffraction study. The 3/NaH system can convert C6H5Br into C6H6 in 32% yield.