trans-[RuBr2(o-diphenylphosphino-N,N-dimethylaniline)(P(p-tolyl)3)] | 1373340-10-3

• 英文名称: trans-[RuBr2(o-diphenylphosphino-N,N-dimethylaniline)(P(p-tolyl)3)]
• CAS: 1373340-10-3
• 化学式: C₄₁H₄₁Br₂NP₂Ru
• 分子量: 870.609
• InChiKey: URQWONWYRDSAAN-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  trans-[RuBr2(o-diphenylphosphino-N,N-dimethylaniline)(P(p-tolyl)3)] 、 硫化氢 、 丙酮 以 丙酮 为溶剂， 以78%的产率得到cis-[RuBr2(o-diphenylphosphino-N,N-dimethylaniline)(P(p-tolyl)3)(H2S)]*acetone
  参考文献：
  名称：

  Ruthenium(II) Thiol and H₂S Complexes: Synthesis, Characterization, and Thermodynamic Properties

  摘要：

  The known, green, five-coordinate species trans-RuCl2(P-N)(PPh3) react with R'SH thiols to give yellow cis-RuCl2(P-N)(PPh3)(R'SH) products (P-N = o-diphenylphosphino-N,N'-dimethylaniline; R' = alkyl). The MeSH and EtSH compounds are structurally characterized, with the former being the first reported for a transition metal MeSH complex, while the thiol complexes with R' = Pr-n, Pr-i, (n)Pn (pentyl), (n)Hx (hexyl), and Bn (benzyl) are synthesized in situ. Other trans-RuX2(P-N) (PR3) complexes (X = Br, I; R = Ph, p-tolyl) are synthesized, and their H2S adducts, of a type reported earlier by our group, are also prepared. Thermodynamic data are presented for the reversible formation of the MeSH and EtSH complexes and the H2S analogues. The (RuCl2)-Cl-II(P-N)(PPh3) complex in solution decomposes under O-2 to form [(RuCl)-Cl-III(P-N)](2)(mu-O)(mu-Cl)(2).

  DOI：

  10.1021/ic3004118
• 作为产物：
  描述：

  dichlorotris(tri(p‑tolyl)phosphine)ruthenium(II) 、 sodium bromide 、 N,N-dimethyl-2-(diphenylphosphino)aniline 以 丙酮 为溶剂， 以53%的产率得到trans-[RuBr2(o-diphenylphosphino-N,N-dimethylaniline)(P(p-tolyl)3)]
  参考文献：
  名称：

  Ruthenium(II) Thiol and H₂S Complexes: Synthesis, Characterization, and Thermodynamic Properties

  摘要：

  The known, green, five-coordinate species trans-RuCl2(P-N)(PPh3) react with R'SH thiols to give yellow cis-RuCl2(P-N)(PPh3)(R'SH) products (P-N = o-diphenylphosphino-N,N'-dimethylaniline; R' = alkyl). The MeSH and EtSH compounds are structurally characterized, with the former being the first reported for a transition metal MeSH complex, while the thiol complexes with R' = Pr-n, Pr-i, (n)Pn (pentyl), (n)Hx (hexyl), and Bn (benzyl) are synthesized in situ. Other trans-RuX2(P-N) (PR3) complexes (X = Br, I; R = Ph, p-tolyl) are synthesized, and their H2S adducts, of a type reported earlier by our group, are also prepared. Thermodynamic data are presented for the reversible formation of the MeSH and EtSH complexes and the H2S analogues. The (RuCl2)-Cl-II(P-N)(PPh3) complex in solution decomposes under O-2 to form [(RuCl)-Cl-III(P-N)](2)(mu-O)(mu-Cl)(2).

  DOI：

  10.1021/ic3004118