[Fe4O2(O2CMe)6(N3)2(1,10-phenanthroline)2] | 697742-27-1

• 英文名称: [Fe4O2(O2CMe)6(N3)2(1,10-phenanthroline)2]
• 英文别名: [Fe4O2(O2CMe)6(N3)2(phen)2]
• CAS: 697742-27-1
• 化学式: C₃₆H₃₄Fe₄N₁₀O₁₄
• 分子量: 1054.11
• InChiKey: SVRVPGLARIRXDW-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  iron perchlorate hexahydrate 、 邻菲罗啉 、 sodium acetate trihydrate 、 sodium azide 以 乙腈 为溶剂， 以42%的产率得到[Fe4O2(O2CMe)6(N3)2(1,10-phenanthroline)2]
  参考文献：
  名称：

  A new example of a tetranuclear iron(III) cluster containing the [Fe4O2]8+ core: preparation, X-ray crystal structure, magnetochemistry and Mössbauer study of [Fe4O2(O2CMe)6(N3)2(phen)2]

  摘要：

  Two synthetic procedures have been employed that allow access to the new tetranuclear cluster [Fe4O2(O2CMe)(6)(N-3)(2)(phen)(2)] (1), where phen is 1, 10-phenanthroline. Complex 1(.)3 MeCN displays an unusual structural asymmetry (observed for the second time) in its [Fe4O2](8divided by) core that can be considered as a hybrid of the bent (butterfly) and planar dispositions of four metal ions seen previously in such compounds with transition metals. Complex 1 has been characterized by variable-temperature magnetic susceptibility studies, and by IR and variable-temperature Fe-57 Mossbauer spectroscopies. Magnetochemical data reveal a diamagnetic ground state (S = 0) with antiferromagnetic body-body and body-wingtip interactions between the iron(Ill) ions of the butterfly core (J(bb) = - 11cm(-1), J(wb) = -70 cm(-1)). Magnetochemical and Mossbauer studies on 1 show that its structural asymmetry has practically no influence on these properties compared with the more symmetric types. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2003.11.005