l5-silane | 28693-40-5

• 英文名称: l5-silane
• CAS: 28693-40-5
• 化学式: H₅Si
• 分子量: 33.1252
• InChiKey: OUCAWZRBSHKXIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.72
• 重原子数：
  1.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  氢气 、 硅烷 以 solid matrix 为溶剂， 生成 氢化硅 、 l5-silane
  参考文献：
  名称：

  Free radicals formed by reaction of silane with hydrogen atoms in rare gas matrices at very low temperatures

  摘要：

  The radicals formed by the reaction of SiH4 with H produced by the photolysis of HI in the matrices of Xe and Kr were investigated by electron spin resonance (ESR) spectroscopy at the temperatures between 4.2 and 100 K. The radicals observed were identified as SiH3 and SiH5. The newly observed radical SiH5 is considered as the intermediate of the reaction SiH4+H→SiH3+H2. The radical had two conformers; both were observed in a Xe matrix, while only one was observed in a Kr matrix. The ESR parameters of these radicals were determined by numerical deconvolution of the observed spectra. The hyperfine coupling of 29Si in silyl radicals isolated in Kr was determined accurately by the present method of the radical formation. The value obtained was 189.5 G instead of 266 G previously reported.

  DOI：

  10.1063/1.449018