((C4H2NC(3,4,5-(MeO)3C6H2))4)CoBr | 204860-97-9

• 英文名称: ((C4H2NC(3,4,5-(MeO)3C6H2))4)CoBr
• CAS: 204860-97-9
• 化学式: C₅₆H₅₂BrCoN₄O₁₂
• 分子量: 1111.95
• InChiKey: PKORWUZTIKTVTP-FROCSNILSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  六甲基磷酰三胺 、 ((C4H2NC(3,4,5-(MeO)3C6H2))4)CoBr 在 甲基锂 作用下， 以 四氢呋喃 、 六甲基磷酰三胺 为溶剂， 以51%的产率得到((C4H2NC(3,4,5-(MeO)3C6H2))4)Co(PO(NMe2)2)
  参考文献：
  名称：

  Synthesis of Novel Cobalt(III) Porphyrin−Phosphoryl Complexes

  摘要：

  Novel porphyrinato[phosphoryl] cobalt(III) complexes were synthesized unexpectedly through the reaction of BrCoIII(por) (por = porphyrinato dianion) with Me3SiLi (MeLi-Me6Si2-HMPA) and MeLi in HMPA at -78 degrees C. Phosphoryl complexes were also synthesized from HMPA-K and the appropriate organophosphoryl chloride-K. As a result, Me3SiLi may not always be an appropriate silylating agent for bulky organometallic electrophiles.

  DOI：

  10.1021/om9705315
• 作为产物：
  描述：

  Co^(II)5,10,15,20-tetra(3,4,5-trimethoxyphenyl)porphyrin 、 氢溴酸 以 甲醇 、 氯仿 、 水 为溶剂， 以92%的产率得到((C4H2NC(3,4,5-(MeO)3C6H2))4)CoBr
  参考文献：
  名称：

  Synthesis of Novel Cobalt(III) Porphyrin−Phosphoryl Complexes

  摘要：

  Novel porphyrinato[phosphoryl] cobalt(III) complexes were synthesized unexpectedly through the reaction of BrCoIII(por) (por = porphyrinato dianion) with Me3SiLi (MeLi-Me6Si2-HMPA) and MeLi in HMPA at -78 degrees C. Phosphoryl complexes were also synthesized from HMPA-K and the appropriate organophosphoryl chloride-K. As a result, Me3SiLi may not always be an appropriate silylating agent for bulky organometallic electrophiles.

  DOI：

  10.1021/om9705315