[Au(N-methylglycinedithiocarbamate)Br2] | 850219-07-7

• 英文名称: [Au(N-methylglycinedithiocarbamate)Br2]
• 英文别名: [Au(sarcosinedithiocarbamate)Br2]
• CAS: 850219-07-7
• 化学式: C₄H₆AuBr₂NO₂S₂
• 分子量: 521.004
• InChiKey: KEALRJVLCDDZDA-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Au(N-methylglycinedithiocarbamate)Br2] 以 neat (no solvent, solid phase) 为溶剂， 生成 金
  参考文献：
  名称：

  Gold(III) dithiocarbamate derivatives of N-methylglycine: An experimental and theoretical investigation

  摘要：

  The synthesis and characterization of the gold(III) complexes [(HSDT)AuX2] and [(HSDT)(2)Au]X (X = Cl, Br; HSDT = sarcosinedithiocarbamate (N-methylglycinedithiocarbamate)) are reported. In the discussed compounds coordination takes place through the sulfur atoms in a square-planar geometry around the gold(III) metal center. The characterization of the complexes has been carried out by means of elemental analysis, conductance measurements, FT-IR, H-1 and C-13 NMR spectroscopy, and thermogravimetric analysis. In addition, the molecular structure of the 1:1 metal-to-ligand complexes has been further investigated by means of density functional calculations, confirming the conclusions reached upon application of the other chemical characterization techniques. The complex [(HSDT)(3)Au] has been also synthesized and characterized by mass spectrometry, FT-IR, NMR and X-ray photoelectron spectroscopy, even if a definitive determination of its structure has not been undoubtedly accomplished. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.12.015
• 作为产物：
  描述：

  四溴金(III)酸钾二水合物 、 barium N-methylglycine dithiocarbamate trihydrate 、 氢溴酸 在 Na₂CO₃ 作用下， 以 水 为溶剂， 以80%的产率得到[Au(N-methylglycinedithiocarbamate)Br2]
  参考文献：
  名称：

  Gold(III) dithiocarbamate derivatives of N-methylglycine: An experimental and theoretical investigation

  摘要：

  The synthesis and characterization of the gold(III) complexes [(HSDT)AuX2] and [(HSDT)(2)Au]X (X = Cl, Br; HSDT = sarcosinedithiocarbamate (N-methylglycinedithiocarbamate)) are reported. In the discussed compounds coordination takes place through the sulfur atoms in a square-planar geometry around the gold(III) metal center. The characterization of the complexes has been carried out by means of elemental analysis, conductance measurements, FT-IR, H-1 and C-13 NMR spectroscopy, and thermogravimetric analysis. In addition, the molecular structure of the 1:1 metal-to-ligand complexes has been further investigated by means of density functional calculations, confirming the conclusions reached upon application of the other chemical characterization techniques. The complex [(HSDT)(3)Au] has been also synthesized and characterized by mass spectrometry, FT-IR, NMR and X-ray photoelectron spectroscopy, even if a definitive determination of its structure has not been undoubtedly accomplished. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.12.015