tetra-n-butylammoniumtetrabromo-nitridorhenate(VI) | 201539-07-3

• 英文名称: tetra-n-butylammoniumtetrabromo-nitridorhenate(VI)
• CAS: 201539-07-3
• 化学式: Br₄NRe*C₁₆H₃₆N
• 分子量: 762.298
• InChiKey: RGWMEBJCNUXZSY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tetra-n-butylammoniumtetrachloro-nitridorhenate(VI) 、 氢溴酸 以 乙腈 为溶剂， 以90%的产率得到tetra-n-butylammoniumtetrabromo-nitridorhenate(VI)
  参考文献：
  名称：

  An electron paramagnetic resonance study of tetra-n-butylammoniumtetrabromo-nitridorhenate(VI), [(n-C4H9)4N][ReNBr4]

  摘要：

  Electron paramagnetic resonance spectroscopic investigations of tetra-n-butylammoniumtetrabromo-nitridorhenate (VI), [(n-C4H9)(4)N]-[ReNBr4], having a 5d(1) configuration, in liquid and frozen solution, are reported. In the polycrystalline samples very complex Re-185,Re-187 and Br-79,Br-81 hyperfine patterns are observed. Hyperfine and ligand hyperfine interactions are used to characterize the bonding properties in the molecular orbital of the unpaired electron and are compared with the results obtained from extended Huckel theory molecular orbital (EHT-MO) calculations. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05906-9