pentacarbonyl(triphenylphosphine)manganese(I) cation | 54039-45-1

• 英文名称: pentacarbonyl(triphenylphosphine)manganese(I) cation
• CAS: 54039-45-1
• 化学式: C₂₃H₁₅MnO₅P
• 分子量: 457.281
• InChiKey: QBZAFONTGDMLLD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  pentacarbonyl(triphenylphosphine)manganese(I) cation 以 四氢呋喃 为溶剂， 生成 羰基镁
  参考文献：
  名称：

  Kuchynka; Amatore; Kochi, Inorganic Chemistry, 1986, vol. 25, # 23, p. 4087 - 4097

  摘要：

  DOI：
• 作为产物：
  描述：

  (乙腈)五羰基锰(I)四氟硼酸盐 在 三苯基膦 作用下， 以 乙腈 为溶剂， 生成 pentacarbonyl(triphenylphosphine)manganese(I) cation
  参考文献：
  名称：

  Cis labilization of ligand dissociation. 7. Substitution reactions of acetonitrilepentacarbonylmanganese(I). Cis labilization via nucleophilic attack at metal-bound carbonyl

  摘要：

  DOI：

  10.1021/ja00539a008

文献信息

• Formation of metal-metal bonds by ion-pair annihilation. Dimanganese carbonyls from manganate(I-) anions and manganese(I) cations
  作者：K. Y. Lee、D. J. Kuchynka、J. K. Kochi

  DOI：10.1021/om00152a010

  日期：1987.9.1
• Group- and electron-transfer reactions of tetracarbonylferrate(2-)
  作者：Yueqian Zhen、Jim D. Atwood

  DOI：10.1021/om00054a047

  日期：1991.8

  Reactions of Fe(CO)4(2-) with metal carbonyl complexes lead to distinct mechanisms. Reaction with metal carbonyl cations gives a two-electron process that we interpret as a CO2+ transfer. Reaction with Mn2(CO)10 occurs by a single-electron transfer producing Fe2(CO)8(2-) and Mn(CO)5-. Reaction with Mn(CO)5Br also occurs by a single-electron transfer. Reaction with Re(CO)5Br could be either SET or direct nucleophilic displacement. Kinetic studies are reported for several reactions.
• Generation of metal formyl complexes using nickel and platinum hydrides as reducing agents
  作者：Alex Miedaner、Daniel L. DuBois、Calvin J. Curtis、R. Curtis Haltiwanger

  DOI：10.1021/om00026a014

  日期：1993.2

  The five-coordinate nickel hydride complex [Ni(dmpe)2H]PF6, (1) [dmpe = 1,2-bis-(dimethylphosphino)ethane] was synthesized by protonation of Ni(dmpe)2 with NH4PF6. The platinum analog, [Pt(dmpe)2H]PF6 (2), and [Pt(depe)2H]PF6 (3) [depe = 1,2-bis(diethylphos-phino)ethane] were synthesized by reduction of the corresponding Pt(II) complexes with NaBH4 on alumina. Complexes 1 and 3 can also be synthesized electrochemically. Reduction of Ni-(dmpe)2(2+) by two electrons in the presence of ammonium ion generates 1, and reduction of Pt(depe)2(2+) in methanol or wet acetonitrile produces 3. These hydrides react with a variety of cationic metal carbonyl complexes to produce known metal formyl complexes. The structure of 3 was determined by X-ray diffraction. Complex 3 crystallizes in a monoclinic unit cell with P2(1)/c symmetry with a = 14.258 (4) angstrom, b = 9.648 (3) angstrom, c = 21.898 (5) angstrom, beta = 91.17 (2)-degrees, V = 3011.7 (14) angstrom3, Z = 4, and d(calcd) = 1.662 g/cm3. Full-matrix least-squares refinement converged with residuals R = 4.52% and R(w) = 5.90%.