[(η5-C5Me5)iron(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)]Cl | 389063-84-7

• 英文名称: [(η5-C5Me5)iron(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)]Cl
• CAS: 389063-84-7
• 化学式: C₃₆H₃₉FeP₆*Cl
• 分子量: 748.848
• InChiKey: JHZXKZKECZTPPZ-RPVCDRRKSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(η5-C5Me5)iron(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)]Cl 、 四苯硼钠 以 四氢呋喃 、 乙醇 为溶剂， 以80%的产率得到[(η5-C5Me5)iron(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)] tetraphenylborate
  参考文献：
  名称：

  Synthesis of Exceptionally Stable Iron and Rutheniumη1-tetrahedro-Tetraphosphorus Complexes: Evidence for a Strong Temperature Dependence of M−P4 π Back Donation

  摘要：

  At variance with white phosphorus, the most reactive allotrope of the element, which is unstable and ignites spontaneously in air, the new η1 -tetrahedro-tetraphosphorus complexes [Cp*M(PR3 )2 (η1 -P4 )]Y (M=Fe, Ru; Y=Cl, PF6 , BPh4 , BAr$\rm{^{\prime }_{4}}$; Cp*=C5 Me3 the structure of the [Cp*Fe(Ph2 PCH2 CH2 PPh2 )(η1 -P4 )]+ ion is depicted) exhibit a surprising and unprecedented thermal stability and an astonishing reluctance to react with oxygen and other oxidants.

  DOI：

  10.1002/1521-3773(20011015)40:20<3910::aid-anie3910>3.0.co;2-2
• 作为产物：
  描述：

  yellow phosphorus 、 (1,2,3,4,5-pentamethylcyclopentadienyl)(1,2-bis(diphenylphosphino)ethane)iron(II)Cl 以 四氢呋喃 、 乙醇 、 正己烷 为溶剂， 以80%的产率得到[(η5-C5Me5)iron(Ph2PCH2CH2PPh2)(η1-tetrahedro-tetraphosphorus)]Cl
  参考文献：
  名称：

  Synthesis of Exceptionally Stable Iron and Rutheniumη1-tetrahedro-Tetraphosphorus Complexes: Evidence for a Strong Temperature Dependence of M−P4 π Back Donation

  摘要：

  At variance with white phosphorus, the most reactive allotrope of the element, which is unstable and ignites spontaneously in air, the new η1 -tetrahedro-tetraphosphorus complexes [Cp*M(PR3 )2 (η1 -P4 )]Y (M=Fe, Ru; Y=Cl, PF6 , BPh4 , BAr$\rm{^{\prime }_{4}}$; Cp*=C5 Me3 the structure of the [Cp*Fe(Ph2 PCH2 CH2 PPh2 )(η1 -P4 )]+ ion is depicted) exhibit a surprising and unprecedented thermal stability and an astonishing reluctance to react with oxygen and other oxidants.

  DOI：

  10.1002/1521-3773(20011015)40:20<3910::aid-anie3910>3.0.co;2-2