bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury | 64147-82-6

• 英文名称: bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury
• 英文别名: bis(1,7-dicarba-closo-dodecaborane-9-yl) mercury；bis(m-carborane-9-yl)mercury(II)；bis(m-carboran-9-yl)mercury；di(m-carborane-9-yl)mercury
• CAS: 64147-82-6
• 化学式: C₄H₂₂B₂₀Hg
• 分子量: 487.029
• InChiKey: CRQGSLVEKTYBKW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury 在 tris(triphenylphosphine)rhodium(l) chloride sodium chloride 作用下， 以 六甲基磷酰三胺 为溶剂， 以62.4%的产率得到9-(9-m-CB19H10CH)-1.7-C2B10H11
  参考文献：
  名称：

  Zakharkin, L. I.; Krainova, N. Yu.; Pisareva, I. V., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1985, vol. 15, p. 655 - 662

  摘要：

  DOI：
• 作为产物：
  描述：

  1,7-C2B10H11-9-HgOCOCF3 在 potassium trifluoroacetate 作用下， 以 丙酮 为溶剂， 以70%的产率得到bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury
  参考文献：
  名称：

  Electrochemical symmetrization of carboranylmercury salts

  摘要：

  DOI：

  10.1016/0022-328x(85)88023-2
• 作为试剂：
  描述：

  四氯化碳 、 1,2,4,5-四甲基-3-亚硝基苯 在 bis(1,7-dicarba-closo-dodecaboran(12)-yl-1)mercury 、 1,1,1-trichloro-3-iodo-propane 作用下， 生成
  参考文献：
  名称：

  ESR determination of the rate constant for the abstraction of chlorine from CCl4 by telomeric CCl3(CH2CH2)n . (n=1?3) radicals

  摘要：

  DOI：

  10.1007/bf00949939

文献信息

• Mercuration ofB(9)-substitutedmeta- andortho-carboranes
  作者：A. Ya. Usyatinsky、K. V. Budkina、P. V. Petrovskii、V. I. Bregadze

  DOI：10.1007/bf00698511

  日期：1995.4

  The mercuration of substituted R2C2B10H9X-9 type carboranes (where R=m-H, X= Cl, Br, I, Me; R=o-H, X=Me) was studied. It was found that mercury atoms add to the boron atoms in position 10 ofmeta-carboranes and in position 12 ofortho-carboranes,i.e., to the boron atoms adjacent to the boron atom bonded to the X substituent. Symmetrical (R2C2B10H8X)2Hg type derivatives were obtained. It was shown that

  研究了取代的 R2C2B10H9X-9 型碳硼烷（其中 R=mH，X=Cl、Br、I、Me；R=oH，X=Me）的汞化。发现汞原子加到间碳硼烷的10位和邻位碳硼烷的12位的硼原子上，即加到与与X取代基键合的硼原子相邻的硼原子上。获得了对称的 (R2C2B10H8X)2Hg 型衍生物。结果表明，它们可用作金属转移反应的起始原料。
• A new type of poly metallic chain compounds: carboranyl derivatives of thallium (iii) containing a B-Tl-transition metal bond sequence
  作者：A. Ya. Usyatinskii、G. Z. Suleimanov、E. A. Zul'fugarly、V. A. Antonovich、V. I. Bregadze、I. P. Beletskaya

  DOI：10.1007/bf00698452

  日期：1993.3

  The interaction of NaM(CO)5 (M=Mn, Re) with (m-H2C2B10H9-9)TlCl2 in THF yields the stable polymetallic chain compounds (m-H2C2B10H9-9)Tl(Cl)M(CO)5. The stability of the compounds obtained is compared to that of the analogous (B-carboranyl)mercury derivatives.

  NaM(CO)5 (M=Mn, Re) 与 (m-H2C2B10H9-9)TlCl2 在 THF 中的相互作用产生稳定的多金属链化合物 (m-H2C2B10H9-9)Tl(Cl)M(CO)5。将所得化合物的稳定性与类似的（B-碳硼烷基）汞衍生物的稳定性进行比较。
• Homolytic Reactive Mass Spectrometry of Fullerenes: Interaction of C₆₀ and C₇₀ with Organo- and Organoelement Mercurials in the Electron Impact Ion Source of a Mass Spectrometer; EPR, CIDEP, and MS Studies of Several Analogous Reactions of C₆₀ Performed in Solution
  作者：Yury I. Lyakhovetsky、Elena A. Shilova、Vasily V. Bashilov、Viatcheslav I. Sokolov、Yuri S. Nekrasov、Boris L. Tumanskii

  DOI：10.1021/jp906058q

  日期：2009.12.10

  process proceeding via their molecular ions. In line with the results obtained in the IC, C60 reacts with Ph2Hg and (o-carborane-9-yl)2Hg under UV-irradiation in benzene and toluene solutions to furnish phenyl and carboranyl derivatives of the fullerene, respectively, some also containing the acquired hydrogen atoms. EPR monitoring of the processes has shown the formation of phenylfullerenyl and o-carborane-9-yl-fullerenyl

  C 60与有机和有机元素汞（CF 3 HgBr，PhHgBr，p -CH 3 C 6 H 4 HgBr，p -CH 3 OC 6 H 4 HgCl，CF 3 HgPh，Ph 2 Hg，（邻-甲硼烷- 9-基）2 Hg，（间-碳硼烷-9-基）2 Hg，（对-碳硼烷-9-基）2 Hg和（m-在250-300°C时，质谱仪的电子碰撞（EI）离子源的电离室（IC）中的甲硼烷-9-基）HgCl）导致相应的有机或有机元素自由基从汞离子转移到富勒烯。一些过程伴随着氢的添加。C 70与Ph 2 Hg和（邻-甲硼烷-9-基）2反应汞在300°C时的作用相似。对于反应考虑均质反应路径。这表明热和EI引发了汞的均相解离，形成中间有机或有机元素自由基，随后它们与IC金属壁上的富勒烯相互作用。当涉及EI时，解离被认为是通过汞试剂的超激发态（电子激发能高于第一电离能的激发态）发生的，该过程可能通过其分子离子进行。与IC中获得的结果一致，C
• ESR study of spin-adducts of boron-centered carboranyl radicals with fullerene-60 and fullerene-70
  作者：B. L. Tumanskii、V. V. Bashilov、S. P. Solodovnikov、N. N. Bubnov、V. I. Sokolov

  DOI：10.1007/bf01151311

  日期：1995.9

  Spin-adducts of boron-centered radicals, derivatives ofm-carboran-12, with fullerenes C60 and C70 have been studied by ESR spectroscopy. Constants of hyperfine splitting (HFS) of an unpaired electron with10B and11B nuclei have been determined from the ESR spectra of C60-B10H9C2H2 radicals. Three isomeric spin-adducts were detected with different HFS constants with11B, andg-factors were detected in

  已经通过 ESR 光谱研究了硼中心自由基、m-carboran-12 衍生物与富勒烯 C60 和 C70 的自旋加合物。已从 C60-B10H9C2H2 自由基的 ESR 光谱确定了具有 10B 和 11B 核的未配对电子的超精细分裂 (HFS) 常数。在B10H9C2H2与C70的反应中检测到三种异构的自旋加合物，其与11B具有不同的HFS常数。
• Zakharkin, L. I.; Pisareva, I. V., Journal of general chemistry of the USSR, 1981, vol. 51, p. 1084 - 1091
  作者：Zakharkin, L. I.、Pisareva, I. V.

  DOI：——

  日期：——