(O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnFe(CO)4 | 175855-67-1

• 英文名称: (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnFe(CO)4
• CAS: 175855-67-1
• 化学式: C₃₄H₅₂FeN₆O₆Sn
• 分子量: 815.38
• InChiKey: KSWRUPQNVBMZGQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  五羰基铁 、 bis[2,4,6-tris(dimethylaminomethyl)phenoxy]-stannylene 以 not given 为溶剂， 生成 (O(2,4,6-tris((dimethylamino)methyl)phenyl))2SnFe(CO)4
  参考文献：
  名称：

  具有MO键的新型二价锗，锡和铅化合物

  摘要：

  合成新的稳定的二价锗，锡和铅均质物种（ArO）2M：（ArO = 2,4,6-[（CH3）2NCH2] 3C6H2O; M = Ge（1），Sn（2），Pb（3 ），Ge（OSO2CF3）2·C4H8O2（4）和杂配物M（OAr）[N（SiMe3）2]（M = Ge（5），Sn（6））。并从1和2开始获得胚硫磷（ArO）2M = X（X = NSiMe3，S）和金属（II）-过渡金属配合物。

  DOI：

  10.1016/0020-1693(95)04977-0

文献信息

• Low coordinate germanium and tin compounds (ArO)2ME and (ArO)2MM′Ln M=Ge, Sn; E=S, Se, –NSiMe3 M′=Cr, W, Fe, Pt [Ar=2,4,6-tris((dimethylamino)methyl)phenyl-]
  作者：Jacques Barrau、Ghassoub Rima、Tajani El Amraoui

  DOI：10.1016/s0022-328x(98)00743-8

  日期：1998.11

  The reactions of the divalent species (ArO)(2)M (Ar = 2,4,6-[(CH3)(2)NCH2](3)C6H2; M = Ge, Sn) with either Me3SiN3, elemental S-8, Se or transition metal complexes M'(CO)(n + 1) (M' = Fe, n = 4; M' = Cr, W; n = 5) (Ph3P)(2)Pt . C2H4 have resulted in the isolation of either the new stable formal metallanimines (ArO)(2)M=N-SiMe3, germanethione, -selone (ArO)(2)Ge=E (E = S, Se) (the expected formations of the stannanethione and -selone were not observed), or the (ArO)(2)M=M'(CO)(n), (ArO)(2)M=Pt(PPh3)(2) complexes, respectively. The direct oxidation of the (ArO)(2)M species with various oxidizing agents led to the formation of the corresponding metalloxanes [(ArO)(2)M-O-](2). All of the chalcogenido- and transition metal-metal 14 complexes have been physicochemically and chemically characterized. The reactions of the (ArO)(2)Ge=E (E = S, Se) compounds with 3,5-di-tert-butyl-1,2-benzoquinone produced, by extrusion of sulfur or selenium, the dioxametalloles corresponding to the formal addition of the divalent species (ArO)(2)M to the benzoquinone. A substitution reaction of chalcogen (S/Se) has been observed permitting to go from germaneselone to germanethione. (C) 1998 Elsevier Science S.A. All rights reserved.