tetrachloroarsonium(V) hexafluoroarsenate(V) | 16871-69-5

• 英文名称: tetrachloroarsonium(V) hexafluoroarsenate(V)
• 英文别名: tetrachloroarsonium hexafluoroarsenate；Hexafluoroarsenic(1-);tetrachloroarsanium
• CAS: 16871-69-5
• 化学式: AsCl₄*AsF₆
• 分子量: 405.646
• InChiKey: SNZGPEXXCSDWHN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.52
• 重原子数：
  12
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  tetrachloroarsonium(V) hexafluoroarsenate(V) 以 neat (no solvent, gas phase) 为溶剂， 生成 Dichloro(trifluoro)-lambda~5~-arsane
  参考文献：
  名称：

  Minkwitz; Prenzel; Schardey, Inorganic Chemistry, 1987, vol. 26, # 16, p. 2730 - 2732

  摘要：

  DOI：
• 作为产物：
  描述：

  三氟化砷 在 Cl₂ 作用下， 生成 tetrachloroarsonium(V) hexafluoroarsenate(V)
  参考文献：
  名称：

  Claus, F.; Minkwitz, R., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为试剂：
  描述：

  1,2,3,4,5,6,7,8-八硫杂环辛烷 、 二氧化硫 、 五氟化砷 在 tetrachloroarsonium(V) hexafluoroarsenate(V) 作用下， 以 liquid sulphur dioxide 为溶剂， 以>99的产率得到
  参考文献：
  名称：

  Halogen-facilitated preparation of S₄(AsF₆)₂·xSO₂(x⩽ 1) and S₄(Sb₂F₁₁)₂, and a convenient synthesis of Se₄(AsF₆)₂and Se₄(Sb₂F₁₁)₂

  摘要：

  Sulfur reacted with an excess of AsF5 at room temperature in the presence of a trace amount of halogen (X2 = Cl2, Br2 or I2) or AsCl4AsF6 in SO2 to give S4(AsF6)2.xSO2 (x less-than-or-equal-to 1) quantitatively in a few minutes. A similar, but slower, reaction with SbF5 in SO2 or AsF3 at room temperature gave quantitative yields of S4(Sb2F11)2. The vibrational spectra of these salts with tentative assignments are reported. The corresponding preparations of Se4(AsF6)2 and Se4(Sb2F11)2 are also greatly facilitated by the presence of traces of halogen. Reactions of sulfur (or selenium) with SbF5 with and without traces of X2 in SO2 designed to give M4(SbF6)2 (M = S or Se) gave products that contained M4(2+), an unidentified Sb(v) fluoronion and some Sb(III)-containing species. A comparative study was made on the effect of solvent, oxidising agent and facilitating reagent on the course of reaction. Possible reaction pathways for oxidation of sulfur (or selenium) by AsF5 (or SbF5) with and without the addition of traces of X2 or AsCl4AsF6 have been proposed.

  DOI：

  10.1039/dt9920000503

文献信息

• The preparation and characterization of SeCl₃SbF₆, improved syntheses of MCl₃(As/Sb)F₆ (M = S, Se), and the X-ray crystal structure determination of SeCl₃AsF₆ and a new phase of SBr₃SbF₆
  作者：Jack Passmore、Paul D. Boyle、Gabriele Schatte、Todd Way、T. Stanley Cameron

  DOI：10.1139/v96-184

  日期：1996.9.1

  Alternative and, in some cases, improved syntheses of the salts MX₃(As/Sb)F₆ (M = S, Se) and SCl₃(SbCl₆/AlCl₄) are described. In addition, the synthesis of SeCl₃SbF₆ is reported. The compounds were characterized by FT–Raman spectroscopy and the X-ray crystal structures of SeCl₃AsF₆ (also ⁷⁷Se NMR) and a new phase of SBr₃SbF₆ were determined. Crystals of SeCl₃AsF₆ and SBr₃SbF₆ are monoclinic, space group P2₁/c with [values for SBr₃SbF₆ in brackets] a = 7.678(1) [8.137(1)] Å, b = 9.380(3) [9.583(2)] Å, c = 11.920(3) [12.447(2)] Å, β = 98.19(2)° [97.36(1)]°, V = 849.72(3) [962.6(3)] ų,z = 4, D_x = 2.925 [3.502] Mg m⁻³, R = 0.0525 [0.055], and R_w = 0.0554 [0.060] for 1151 [1472] observed reflections. Key words: MX₃⁺ salts, FT–Raman spectroscopy, X-ray crystal structures of SeCl₃AsF₆, SBr₃SbF₆, and preparation of SeCl₃SbF₆.

  描述了MX₃(As/SB)F₆（M = S，Se）和SCl₃(SBCl₆/AlCl₄)盐的替代和在某些情况下改进的合成方法。此外，报道了SeCl₃SBF₆的合成方法。这些化合物通过FT-Raman光谱学进行了表征，并确定了SeCl₃AsF₆（还使用了⁷⁷Se NMR）和新相SBr₃SBF₆的X射线晶体结构。SeCl₃AsF₆和SBr₃SBF₆的晶体为单斜晶系，空间群为P2₁/c，参数为a = 7.678(1) [8.137(1)] Å，b = 9.380(3) [9.583(2)] Å，c = 11.920(3) [12.447(2)] Å，β = 98.19(2)° [97.36(1)]°，V = 849.72(3) [962.6(3)] ų，z = 4，D_x = 2.925 [3.502] Mg m⁻³，R = 0.0525 [0.055]，R_w = 0.0554 [0.060]，对于1151 [1472]个观察到的反射。关键词：MX₃⁺盐，FT-Raman光谱学，SeCl₃AsF₆，SBr₃SBF₆的X射线晶体结构，以及SeCl₃SBF₆的制备。
• Über die Reaktion von Chlornitrat ClONO₂ mit PCl₃, AsCl₃, SbCl₃ und AsCl₄ ⁺AsF₆ ^- / On the Reaction of Chlorine Nitrate ClONO₂, with PCl₃, AsCl₃, SbCl₃ and AsCl₄ ⁺AsF₆ ^-
  作者：Rolf Minkwitz、Thomas Hertel、Ralf Meier

  DOI：10.1515/znb-1996-0802

  日期：1996.8.1

  The reaction of ClONO₂ with PCl₃ yields POCl₃ and NO₂ ⁺NO₃ ^- . With AsCl₃ chlorine nitrate forms a compound of the analytical composition “AsCl₂(NO₃)₃” in contrast to SbCl₃, which does not react with ClONO₂. The reaction of ClONO₂ with AsCl₄ ⁺AsF₆ ^- was reported to yield As(ONO₂)₄ ⁺AsF₆ ^-. We found no reaction below 273 K. Reaction at 293 K yields NO₂ ⁺AsF₆ ^- as solid product. SbCl₅ does react, but the reaction yields no reproduceable products.

  ClONO₂与PCl₃的反应产生POCl₃和NO₂⁺NO₃^-。与AsCl₃反应，氯酸盐形成了分析组成为“AsCl₂(NO₃)₃”的化合物，与不与ClONO₂反应的SbCl₃形成对比。报道ClONO₂与AsCl₄⁺AsF₆^-的反应生成As(ONO₂)₄⁺AsF₆^-。我们发现在273K以下没有反应。在293K时的反应产生固体产物NO₂⁺AsF₆^-。SbCl₅会发生反应，但反应产物不可重现。
• Experimental and Theoretical Characterization of Cationic, Neutral, and Anionic Binary Arsenic and Antimony Azide Species
  作者：Konstantin Karaghiosoff、Thomas M. Klapötke、Burkhard Krumm、Heinrich Nöth、Thomas Schütt、Max Suter

  DOI：10.1021/ic010463l

  日期：2002.1.1

  Cationic, neutral, and anionic arsenic and antimony halides formed binary arsenic and antimony azide species M(N(3))(4)(+), M(N(3))(4)(-), and M(N(3))(6)(-) (M = As, Sb) upon reaction with trimethylsilyl azide or sodium azide. The compounds were obtained as pure substances or salts, and their identity was established by vibrational spectroscopy and multinuclear NMR spectroscopy and partially by elemental

  阳离子，中性和阴离子砷和锑卤化物形成二元砷和叠氮化锑物质M（N（3））（4）（+），M（N（3））（4）（-）和M（N（ 3））（6）（-）（M = As，Sb）与三甲基硅烷基叠氮化物或叠氮化钠反应后。获得的化合物为纯物质或盐，其身份通过振动光谱和多核NMR光谱确定，部分通过元素分析确定。尝试合成五叠氮化物M（N（3））（5）（M = As，Sb）的尝试由于化合物的自发分解而失败。应用密度泛函理论（B3LYP）计算结构和振动数据。分离出的叠氮化物化合物的振型与计算结果进行了振动分配。从理论上研究了五叠氮化砷和锑的分子结构和振动光谱。这些计算（B3LYP）显示了所有报告化合物的最小结构（NIMAG = 0）。结果表明M（N（3））（4）（+）（M = As，Sb）阳离子表现出理想的S（4）对称性和M（N（3））（6）（-）阴离子（ M = As，Sb）理想的S（6）对称性。六叠氮砷酸盐（V）
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: V: MVol.B1, 82, page 223 - 225
  作者：

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  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ag: MVol.B1, 6.2.1.4, page 321 - 322
  作者：

  DOI：——

  日期：——