Potassium hexa cyanocobaltate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属有机体
• 英文名称: Potassium hexa cyanocobaltate
• 英文别名: cobalt;hexacyanide
• 化学式: C6CoN6-6
• 分子量: 215.04
• InChiKey: RKBAPHPQTADBIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.58
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  143
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为反应物：
  描述：

  氯化锌 、 Potassium hexa cyanocobaltate 以 水 为溶剂， 生成 ZINC hexacyanocobaltate(III)
  参考文献：
  名称：

  Viscosity stable isocyanate-terminated prepolymers and polyoxyalkylene

  摘要：

  含有双金属氰化物配合物或其残留物的聚氧化烷基多元醇，在通过适当的含官能基的起始剂进行双金属氰化物复合物催化的氧烷基化制备聚氧化烷基多元醇时，无需去除催化剂即可保持稳定。从这样的多元醇制备的异氰酸酯末端预聚物与不含双金属氰化物配合物或其残留物的类似预聚物相比，具有惊人的黏度稳定性。

  公开号：

  US05811829A1

文献信息

• Process for preparing metal cyanide complex catalyst
  申请人：Arco Chemical Technology, L.P.

  公开号：US05158922A1

  公开（公告）日：1992-10-27

  Highly active double metal cyanide complex catalysts suitable for use in ring-opening polymerization reactions may be prepared in filterable form by controlling the order of reagent addition, the temperature of the reaction medium, and the stoichiometric ratio of the reactants.

  适用于开环聚合反应的高活性双金属氰化物复合催化剂可以通过控制试剂添加顺序、反应介质温度和反应物的化学计量比来制备可过滤的形式。
• Double metal cyanide complex catalysts
  申请人：ARCO Chemical Technology, L.P.

  公开号：US05470813A1

  公开（公告）日：1995-11-28

  Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. A method of making the improved DMC catalysts, which involves intimately combining the reactants, is also disclosed.

  本发明揭示了改进的双金属氰化物催化剂。本发明的基本非晶态催化剂比具有相当晶体成分的传统DMC催化剂更活性，用该催化剂制备的聚醚醇产品异常清晰，具有异常低的不饱和度，并且不含可检测到的低分子量聚醇杂质。本发明还揭示了一种制备改进的DMC催化剂的方法，该方法涉及密切组合反应物。
• Double metal cyanide catalysts and methods for making them
  申请人：ARCO Chemical Technology, L.P.

  公开号：US05639705A1

  公开（公告）日：1997-06-17

  Improved double metal cyanide (DMC) catalysts useful for making epoxide polymers are disclosed. One catalyst is a paste of a double metal cyanide (DMC) compound, an organic complexing agent, and water. The paste comprises at least about 90 wt. % of particles having a particle size within the range of about 0.1 to about 10 microns as measured by light scattering in polyether polyol dispersions of the catalyst particles. Preferred catalysts have a bimodal particle size distribution. The paste catalyst is more active and simpler to prepare than powder DMC catalysts. Polyols made from the paste catalyst have low unsaturations, low viscosities, and narrow molecular weight distributions, and are useful in making a variety of polyurethane products.

  本发明公开了用于制造环氧聚合物的改进型双金属氰化物（DMC）催化剂。其中一种催化剂是由双金属氰化物（DMC）化合物、有机络合剂和水组成的浆糊。该浆糊包含至少约90重量％的粒子，其粒径在约0.1至约10微米之间，通过在催化剂粒子的聚醚多元醇分散体系中进行光散射测量得出。首选催化剂具有双峰粒径分布。与粉末DMC催化剂相比，浆糊催化剂更活性且制备更简单。使用浆糊催化剂制备的聚醇具有低不饱和度、低粘度和窄分子量分布，可用于制造各种聚氨酯产品。
• Highly active double metal cyanide complex catalysts
  申请人：Arco Chemical Technology, L.P.

  公开号：US05712216A1

  公开（公告）日：1998-01-27

  Improved double metal cyanide catalysts are disclosed. The substantially amorphous catalysts of the invention are more active for polymerizing epoxides than conventional DMC catalysts, which have a substantial crystalline component. Polyol products made with the catalysts are unusually clear, have exceptionally low unsaturations, and contain no detectable amount of low molecular weight polyol impurities. Methods of making the improved DMC catalysts are also disclosed. In one method, the reactants are intimately combined to produce a catalyst of the invention. In another method, an organic complexing agent is initially present in the reactant solutions.

  本发明公开了改进的双金属氰化物催化剂。本发明中的非晶态催化剂比具有实质性晶体成分的传统DMC催化剂更活性，用该催化剂制备的聚醚多元醇产品异常清澈，具有异常低的不饱和度，并且不含有可检测到的低分子量聚醇杂质。本发明还公开了制备改进的DMC催化剂的方法。在一种方法中，反应物被密切结合以产生本发明的催化剂。在另一种方法中，有机络合剂最初存在于反应物溶液中。
• Viscosity-stable isocyanate-terminated prepolymers and polyoxyalkylene
  申请人：Arco Chemical Technology, L.P.

  公开号：US05919888A1

  公开（公告）日：1999-07-06

  Polyoxyalkylene polyols containing double metal cyanide complexes or residues thereof as are produced during the preparation of polyoxyalkylene polyols by the double metal cyanide complex catalyzed oxyalkylation of a suitably functional hydric initiator are stable without catalyst removal. Isocyanate-terminated prepolymers prepared from such polyols are surprisingly viscosity-stable relative to similar prepolymers prepared from polyols not containing double metal cyanide complexes or residues thereof.

  含有双金属氰化物复合物或其残留物的聚氧化烷基多元醇在双金属氰化物复合物催化的适当官能羟基引发剂氧烷基化制备聚氧化烷基多元醇期间稳定，无需去除催化剂。从这样的聚醇制备的异氰酸酯末端预聚物与不含双金属氰化物复合物或其残留物的聚醇制备的类似预聚物相比，具有出乎意料的粘度稳定性。