名称:
Preparation and structures of polymeric lanthanide nitrate complexes of CH3C[CH2P(O)Ph2]3
摘要:
The synthesis of complexes between lanthanide nitrates and MeC(CH2P(O)Ph-2)(3) (=L) in ethanol or methanol leads to the formation of polymeric complexes Ln(NO3)(3)L as alcohol solvates. The ligand adopts a chelating-bridging mode. The structures of the complexes La(NO3)(3)L . EtOH and Pr(NO3)(3)L . MeOH are reported and the coordination of L is discussed in terms of that of the related free ligand EtC(CH2P(O)Ph-2)(3). Infrared spectroscopy implies structural differences between the early and later lanthanide complexes. (C) 2004 Elsevier Ltd. All rights reserved.
DOI:
10.1016/j.poly.2004.12.003