有机镁
有机镁是一类重要的化学中间体，在有机合成和制药领域具有重要作用。这类化合物通常指的是含有碳-镁键的有机金属化合物。有机镁化合物在合成中表现出许多优势，包括反应条件温和、易操作等特性。
有机镁化合物主要是通过格氏试剂（R-Mg-X）的形式存在，其中R代表烃基团，X为卤素原子（如氯或溴）。这类化合物可以通过将醇、胺或其他含有活泼氢的化合物与金属镁在无水条件下进行反应来制备。格氏试剂是一类非常强的亲核试剂，在许多有机合成反应中扮演重要角色。
有机镁化合物被广泛应用于有机化学中的偶联反应、还原反应和缩合反应等。它们可以催化多种类型的化学转化，例如用于C-C键形成、醇或卤代烃的官能团化以及碳-碳双键的加成反应等。此外，在制药领域中，通过使用有机镁试剂进行化合物修饰及合成也是十分常见的。
总之，由于其独特的性质和广泛的适用性，有机镁成为有机化学研究中不可或缺的一部分，并且在药物设计与合成过程中发挥着重要作用。
| 中文名称 | 英文名称 | CAS号 | 化学式 | 结构式图片 |
|---|---|---|---|---|
| [3-(1-哌啶基甲基)苯基]溴化镁 | Magnesium bromide 3-[(piperidin-1-yl)methyl]benzen-1-ide (1/1/1) | 480424-82-6 | C12H16BrMgN |
|
| [2-(4-吗啉甲基)苯基]溴化镁 | Magnesium bromide 2-[(morpholin-4-yl)methyl]benzen-1-ide (1/1/1) | 480424-77-9 | C11H14BrMgNO |
|
| [2-(1-哌啶基甲基)苯基]溴化镁 | Magnesium bromide 2-[(piperidin-1-yl)methyl]benzen-1-ide (1/1/1) | 480424-81-5 | C12H16BrMgN |
|
| [2-(1-吡啶甲基)苯基]溴化镁 | Magnesium bromide 2-[(pyrrolidin-1-yl)methyl]benzen-1-ide (1/1/1) | 480424-80-4 | C11H14BrMgN |
|
| O-甲苯基氯化镁 | O-TOLYLMAGNESIUM CHLORIDE | 33872-80-9 | C7H7ClMg |
|
| 9-菲基溴化镁 | Magnesium bromide phenanthren-9-ide (1/1/1) | 71112-64-6 | C14H9BrMg |
|
| 8-苯胺基-1-萘磺酸镁盐 | 18108-68-4 | C16H13MgNO3S |
|
|
| 6-甲氧基-2-萘基溴化镁 | magnesium;6-methoxy-2H-naphthalen-2-ide;bromide | 38046-82-1 | C11H9BrMgO |
|
| 5-氯-2-噻吩基溴化镁 | Magnesium bromide 5-chlorothiophen-2-ide (1/1/1) | 111762-30-2 | C4H2BrClMgS |
|
| 5-氟-2-甲基苯基溴化镁 | Magnesium bromide 5-fluoro-2-methylbenzen-1-ide (1/1/1) | 186496-59-3 | C7H6BrFMg |
|
| 4-苄氧基苯基溴化镁 | Magnesium;phenylmethoxybenzene;bromide | 120186-59-6 | C13H11BrMgO |
|
| 4-硫代苯甲醚溴化镁 | magnesium;methylsulfanylbenzene;bromide | 18620-04-7 | C7H7BrMgS |
|
| 4-甲氧基苯乙烯基氯化镁 | Magnesium chloride 2-(4-methoxyphenyl)ethan-1-ide (1/1/1) | 211115-05-8 | C9H11ClMgO |
|
| 4-甲氧基苄基氯化镁 | Magnesium;1-methanidyl-4-methoxybenzene;chloride | 38769-92-5 | C8H9ClMgO |
|
| 4-甲氧基-2-甲基苯基溴化镁 | Magnesium bromide 4-methoxy-2-methylbenzen-1-ide (1/1/1) | 148706-30-3 | C8H9BrMgO |
|
| 4-甲基-1-萘基溴化镁 | Magnesium bromide 4-methylnaphthalen-1-ide (1/1/1) | 115913-58-1 | C11H9BrMg |
|
| 4-氯-3-氟苯基溴化镁 | Magnesium bromide 4-chloro-3-fluorobenzen-1-ide (1/1/1) | 170793-00-7 | C6H3BrClFMg |
|
| 4-氟苯基溴化镁 | 4-Fluorophenylmagnesium bromide | 352-13-6 | C6H4BrFMg |
|
| 4-氟-3-甲基苯基溴化镁 | Magnesium bromide 4-fluoro-3-methylbenzen-1-ide (1/1/1) | 82297-89-0 | C7H6BrFMg |
|
| 4-正丁基苯基溴化镁 | Magnesium bromide 4-propylbenzen-1-ide (1/1/1) | 87942-08-3 | C9H11BrMg |
|
| 4-(2-四氢-2H-吡喃氧代)苯基溴化镁 | Magnesium bromide 4-[(oxan-2-yl)oxy]benzen-1-ide (1/1/1) | 36637-44-2 | C11H13BrMgO2 |
|
| 3-苄氧基苯基溴化镁 | Magnesium bromide 3-(benzyloxy)benzen-1-ide (1/1/1) | 36281-96-6 | C13H11BrMgO |
|
| 3-甲氧基苯基溴化镁 | Magnesium bromide 3-methoxybenzen-1-ide (1/1/1) | 36282-40-3 | C7H7BrMgO |
|
| 3-甲氧基苄基氯化镁 | Magnesium;1-methanidyl-3-methoxybenzene;chloride | 26905-40-8 | C8H9ClMgO |
|
| 3-甲基苄基氯化镁 | Magnesium chloride (3-methylphenyl)methanide (1/1/1) | 29875-06-7 | C8H9ClMg |
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| 3-甲基-2-噻吩基溴化镁 | Magnesium bromide 3-methylthiophen-2-ide (1/1/1) | 95184-07-9 | C5H5BrMgS |
|
| 3-溴苄基溴化镁 | Magnesium bromide (3-bromophenyl)methanide (1/1/1) | 107549-22-4 | C7H6Br2Mg |
|
| 3-氯苯基溴化镁 | 3-Chlorophenylmagnesium bromide | 36229-42-2 | C6H4BrClMg |
|
| 3-氯-4-氟苯基溴化镁 | Magnesium bromide 3-chloro-4-fluorobenzen-1-ide (1/1/1) | 413589-34-1 | C6H3BrClFMg |
|
| 3-氟苯基溴化镁 | (3-Fluorophenyl) magnesium bromide | 17318-03-5 | C6H4BrFMg |
|
| 3-氟-4-甲氧基苯基溴化镁 | Magnesium bromide 3-fluoro-4-methoxybenzen-1-ide (1/1/1) | 112780-67-3 | C7H6BrFMgO |
|
| 3-氟-4-甲基苯基溴化镁 | Magnesium bromide 3-fluoro-4-methylbenzen-1-ide (1/1/1) | 185077-02-5 | C7H6BrFMg |
|
| 3-噻吩基碘化镁 | Magnesium, iodo-3-thienyl- | 172035-86-8 | C4H3IMgS |
|
| 3-二苯基溴化镁 | Magnesium bromide 1,1'-biphenyl (1/1/1) | 103068-18-4 | C12H9BrMg |
|
| 3-丁烯基溴化镁 | Magnesium;but-1-ene;bromide | 7103-09-5 | C4H7BrMg |
|
| 3-[双(三甲基硅烷基)氨基]苯基氯化镁 | magnesium;N,N-bis(trimethylsilyl)aniline;chloride | 174484-84-5 | C12H22ClMgNSi2 |
|
| 3-(N-BOC-氨甲基)苯基硼酸 | (3-{[(tert-butoxycarbonyl)amino]methyl}phenyl)boronic acid | 199609-62-6 | C12H18BNO4 |
|
| 3,7-二甲基辛基溴化镁 | Magnesium;2,6-dimethyloctane;bromide | 114499-45-5 | C10H21BrMg |
|
| 3,5-双(三氟甲基)苯基溴化镁 | Magnesium bromide 3,5-bis(trifluoromethyl)benzen-1-ide (1/1/1) | 112981-69-8 | C8H3BrF6Mg |
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| 3,5-二甲氧苯基氯化镁 | Magnesium chloride 3,5-dimethoxybenzen-1-ide (1/1/1) | 89981-17-9 | C8H9ClMgO2 |
|
| 3,5-二甲氧基苄基氯化镁 | Magnesium;1-methanidyl-3,5-dimethoxybenzene;chloride | 135808-66-1 | C9H11ClMgO2 |
|
| 3,5-二甲基苯基溴化镁 | 3,5-Dimethylphenylmagnesium bromide | 34696-73-6 | C8H9BrMg |
|
| 3,5-二甲基-4-甲氧基苯基溴化镁 | Magnesium bromide 4-methoxy-3,5-dimethylbenzen-1-ide (1/1/1) | 185416-17-5 | C9H11BrMgO |
|
| 3,5-二氯苯基溴化镁 | Magnesium bromide 3,5-dichlorobenzen-1-ide (1/1/1) | 82297-90-3 | C6H3BrCl2Mg |
|
| 3,5-二氟苯基溴化镁 | Magnesium bromide 3,5-difluorobenzen-1-ide (1/1/1) | 62351-47-7 | C6H3BrF2Mg |
|
| 3,4-二甲氧苯基溴化镁 | Magnesium;1,2-dimethoxybenzene-5-ide;bromide | 89980-69-8 | C8H9BrMgO2 |
|
| 3,4-二氯苯基溴化镁 | Magnesium bromide 3,4-dichlorobenzen-1-ide (1/1/1) | 79175-35-2 | C6H3BrCl2Mg |
|
| 3,4-二氟苯基溴化镁 | Magnesium;1,2-difluorobenzene-5-ide;bromide | 90897-92-0 | C6H3BrF2Mg |
|
| 3,4,5-三甲氧基苯基溴化镁 | Magnesium;1,2,3-trimethoxybenzene-5-ide;bromide | 133095-91-7 | C9H11BrMgO3 |
|
| 3,4,5-三氟苯基溴化镁 | Magnesium bromide 3,4,5-trifluorobenzen-1-ide (1/1/1) | 156006-28-9 | C6H2BrF3Mg |
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