| 57494-62-9

• CAS: 57494-62-9
• 化学式: C₂₂H₃₆O₆
• 分子量: 396.524
• InChiKey: LIJLRKBFZHDDIM-UWLPTTJDSA-N

反应信息

• 作为产物：
  描述：

  在 lithium aluminium tetrahydride 作用下， 以 乙醚 为溶剂， 生成
  参考文献：
  名称：

  Terpenoids. XXXIII. Chemical conversion of enmein into enmelol.

  摘要：

  After several preliminary experiments, enmein (1) was converted into enmelol (2). The route consists of the following steps : (i) Enmein (1) was converted into lactone ester 40 via 3, 8, 9, and 10. (ii) An acyloin product 42 derived from 40 was transformed into 15-kaurene derivative 61, via epoxide 56, 1β-ol 57, acetate 58, and 15-ol 59. (iii) By photosensitized oxygenation of 61, allyl alcohol 62 and αβ-unsaturated ketone 63 were yielded. (iv) Enmelol (2) and 15-epienmelol (69) were derived from 63 and 62, respectively.

  DOI：

  10.1248/cpb.23.858