Synthesis and characterisation of binuclear phosphite complexes of rhodium(I) with bridging azines
作者:Sarada Gopinathan、Sanjeevani A. Pardhy、I.R. Unny、C. Gopinathan
DOI:10.1016/s0020-1693(00)82033-2
日期:1990.3
Abstract Carbonyl ligand substitution in binuclear rhodium(I) complexes such as [Rh(CO)2]2(azine) with trialkyl or triphenylphosphite gave mono- and di-substituted phosphitederivatives, Rh(CO)[P(OR)3]}2(azine) and Rh[P(OR)3]2}2(azine). The complexes have been characterised by elemental analysis, IR and NMR studies. The 1H and 31P NMR spectra of the mono-substituted unsymmetrical azine complex Rh(