trans-bis(ethanedithiolato{2-}-S,S')bis(2-{2-pyridyl}ethylamine)tin(IV) | 142249-31-8

• 英文名称: trans-bis(ethanedithiolato{2-}-S,S')bis(2-{2-pyridyl}ethylamine)tin(IV)
• CAS: 142249-31-8
• 化学式: C₁₈H₂₈N₄S₄Sn
• 分子量: 547.421
• InChiKey: NFEHODGYIUYSHW-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  2-(2-氨乙基)吡啶 、 (1,2-ethanedithiol)₂Sn(IV) 以 neat (no solvent) 为溶剂， 生成 trans-bis(ethanedithiolato{2-}-S,S')bis(2-{2-pyridyl}ethylamine)tin(IV)
  参考文献：
  名称：

  X-ray structural study on spirocyclic bis(ethane-1,2-dithiolato[2−]-S,S′)tin(IV) and its pyridine and 2-(2-pyridyl)ethylamine adducts

  摘要：

  Spirocyclic bis(ethane-1,2-dithiolato[2-]-SS')tin(IV) forms hexacoordinate crystalline complexes with pyridine and 2-(2-pyridyl)ethylamine. The compounds have been prepared by conventional methods and the crystal structures have been determined by an X-ray diffraction study. In the parent compound the tin is tetracoordinate in a highly distorted tetrahedral structure, with a weak intermolecular Sn ... S interaction. On the contrary, the adducts are essentially octahedral about the tin, with longer Sn-S bonds in the five-membered rings SnS2C2. The 2-(2-pyridyl)ethylamine ligand is bonded to the metal through the aminic nitrogen.

  DOI：

  10.1016/s0020-1693(00)80350-3