1,1'-bis(diisopropylboryl)cobaltocenium | 177956-55-7

• 英文名称: 1,1'-bis(diisopropylboryl)cobaltocenium
• CAS: 177956-55-7
• 化学式: C₂₂H₃₆B₂Co
• 分子量: 381.143
• InChiKey: DLTDMAAKYYPCCV-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  吡啶 、 1,1'-bis(diisopropylboryl)cobaltocenium 生成 1,1'-bis(diisopropylboryl)cobaltocenium(pyridine)2
  参考文献：
  名称：

  Bis(boryl)metallocenes. 1. 1,1‘-Bis(diisopropylboryl)cobaltocenium Cation:  A Novel Anion-Binding Ligand

  摘要：

  Three situations are observed when the new cobaltocene derivative Co(C5H4BPr2i)(2) (2) is oxidized. The cobaltocenium salt [2]PF6 (3) is obtained with [FeCp(2)]PF6 as oxidant. With Cu(OH)(2) the inverse chelate [2]OH (4) with a mu-OH group bridging the two boron centers is formed. Oxidation with C2Cl6 gives a zwitterionic chloride (5) with a trigonal and a quaternized boron center; in solution 5 is fluxional.

  DOI：

  10.1021/om960237x