trichloro[η(5)-(trimethylstannyl)cyclopentadienyl]titanium | 71713-66-1

• 英文名称: trichloro[η(5)-(trimethylstannyl)cyclopentadienyl]titanium
• CAS: 71713-66-1
• 化学式: C₈H₁₃Cl₃SnTi
• 分子量: 382.14
• InChiKey: CSGVWQSWXLSWFS-UHFFFAOYSA-K

反应信息

• 作为产物：
  描述：

  bis(trimethylstannyl)cyclopentadiene 、 四氯化钛 以 甲苯 为溶剂， 生成 trichloro[η(5)-(trimethylstannyl)cyclopentadienyl]titanium
  参考文献：
  名称：

  Trichloro[η5-(trimethylstannyl)cyclopentadienyl]titanium

  摘要：

  The title compound, [TiCl3{(CH3)(3)Sn(C5H4)}], is the first structurally characterized complex of an early transition metal with a cyclopentadienyl ligand-bearing stannyl moiety. The Ti-Cp distance of 1.986(4) Angstrom [where Cp is the centroid of the cyclopentadienyl (Cp) ring] is the shortest among the complexes containing the CpTiCl(3) moiety.

  DOI：

  10.1107/s0108270196011365